| Presentation | 2013-12-17 Analysis of effective nitrogen chemical species in oxygen reduction catalysts made from iron cobalt complexes with pyridyl ligands as precursors Masakuni TAKAHASHI, Hidenobu SHIROISHI, Morihiro SAITO, Yumi TANAKA, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Non-platinum oxygen reduction catalysts made from iron cobalt complexes with pyridyl ligands as precursors supported on multi-wall carbon nanotubes were synthesized by heat treatment with ammonia atmospheres. The mechanism of oxygen reduction for the catalysts was investigated by X-ray photoelectron spectroscopy and a rotating ring disk electrode method. The correlation coefficients between effective nitrogen chemical species on the surface of the oxygen reduction catalysts and cathodic current derived from oxygen reduction reaction or 4-electron reduction efficiency were estimated at each potential. It is clarified that the effective nitrogen chemical species depend on the kinds of ligands used in the precursors. The quaternary-type nitrogen species was effective when using 1, 10-phenanthroline as ligands, whereas the pyridine-type nitrogen species was effective when using 2,2'-bipyridine as ligands. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Fuel cell / Oxygen reduction / Non-precious metal catalyst / Effective nitrogen species |
| Paper # | OME2013-78 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 2013/12/10(1days) |
| Place (in Japanese) | (See Japanese page) |
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| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Analysis of effective nitrogen chemical species in oxygen reduction catalysts made from iron cobalt complexes with pyridyl ligands as precursors |
| Sub Title (in English) | |
| Keyword(1) | Fuel cell |
| Keyword(2) | Oxygen reduction |
| Keyword(3) | Non-precious metal catalyst |
| Keyword(4) | Effective nitrogen species |
| 1st Author's Name | Masakuni TAKAHASHI |
| 1st Author's Affiliation | Tokyo National College of Technology() |
| 2nd Author's Name | Hidenobu SHIROISHI |
| 2nd Author's Affiliation | Tokyo National College of Technology |
| 3rd Author's Name | Morihiro SAITO |
| 3rd Author's Affiliation | Tokyo University of Agriculture & Technology |
| 4th Author's Name | Yumi TANAKA |
| 4th Author's Affiliation | Tokyo University of Science |
| Date | 2013-12-17 |
| Paper # | OME2013-78 |
| Volume (vol) | vol.113 |
| Number (no) | 358 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |