Presentation 2013-12-17
In Situ Observation of Direct Electron Transfer Reaction of Cytochrome c Adsorbed on ITO Electrode by Slab Optical Waveguide Spectroscopy
Naoki MATSUDA, Hirotaka OKABE,
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Abstract(in English) In situ observation of direct electron transfer (DET) reaction of cytochrome c immobilized on ITO electrode was performed by slab optical waveguide Spectroscopy. The comparison of the adsorbed amount of cytochrome c estimated from the SOWG absorbance at Soret band peak position and redox peak area in cyclic voltammogram was performed. After several times of washing treatment of the cytochrome c adsorbed on ITO electrode, only Soret band was observed though CV redox peaks disappeared. It is suggested that cytochrome c redox potential shift to the cathodic direction due to adsorption on ITO electrode is the cause of this phenomena.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) slab optical waveguide Spectroscopy / cytochrome c / ITO electrode / direct electron transfer reaction / time-resolved absorption spectra / in situ observation / phosphonic acid self-assembled monolayer
Paper # OME2013-77
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Committee OME
Conference Date 2013/12/10(1days)
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Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) In Situ Observation of Direct Electron Transfer Reaction of Cytochrome c Adsorbed on ITO Electrode by Slab Optical Waveguide Spectroscopy
Sub Title (in English)
Keyword(1) slab optical waveguide Spectroscopy
Keyword(2) cytochrome c
Keyword(3) ITO electrode
Keyword(4) direct electron transfer reaction
Keyword(5) time-resolved absorption spectra
Keyword(6) in situ observation
Keyword(7) phosphonic acid self-assembled monolayer
1st Author's Name Naoki MATSUDA
1st Author's Affiliation Measurement Solution Research Center, National Institute of Advanced Industrial Science and Technology (AIST)()
2nd Author's Name Hirotaka OKABE
2nd Author's Affiliation Measurement Solution Research Center, National Institute of Advanced Industrial Science and Technology (AIST)
Date 2013-12-17
Paper # OME2013-77
Volume (vol) vol.113
Number (no) 358
Page pp.pp.-
#Pages 5
Date of Issue