Presentation 2013-06-21
Effect of N_2O doping on the properties of ZnO thin films grown using high-energy H_2O generated by a catalytic reaction
Naoya YAMAGUCHI, Yuuki OOHASHI, Eichi NAGATOMI, Yasuhiro TAMAYAMA, Takahiro KATO, Kanji YASUI,
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Abstract(in English) ZnO films were grown using a reaction between an alkylzinc (DMZn) gas and high-energy H_2O, the latter is generated by a Pt-catalyzed exothermic H_2-O_2 reaction. During the film growth, N_2O gas was added in the reaction zone. In this study, the influence of the N_2O gas supply during the film growth on the properties of the ZnO films was investigated. The ZnO epitaxial films were directly grown on a-Al_2O_3 substrates at a substrate temperature of 773K for 60 min without any buffer layer. Although all films showed an n-type character, the electron mobility of N_2O doped (3.2×10^<-3> Pa) film at RT (290 K) was 234cm^2/Vs, while that of non-doped ZnO film was 207cm^2/Vs. The mobility of the N_2O doped film (234 cm^2/Vs at RT) increases to 1100 cm^2/Vs at 100 K. Electron concentrations at RT of all films were 4-6×10^<16>cm^<-3>. It was considered that a part of the nitrogen acceptor compensated the donor impurities and the intrinsic donor impurities caused by the defects were also reduced by the nitrogen atoms in view of the small electron concentration and the large electron mobility for N_2O doped ZnO films.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) ZnO / catalytic reaction / high-energy H_2O / N_2O dope / Hall mobility / PL spectra
Paper # EMD2013-22,CPM2013-37,OME2013-45
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Conference Information
Committee EMD
Conference Date 2013/6/14(1days)
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Registration To Electromechanical Devices (EMD)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Effect of N_2O doping on the properties of ZnO thin films grown using high-energy H_2O generated by a catalytic reaction
Sub Title (in English)
Keyword(1) ZnO
Keyword(2) catalytic reaction
Keyword(3) high-energy H_2O
Keyword(4) N_2O dope
Keyword(5) Hall mobility
Keyword(6) PL spectra
1st Author's Name Naoya YAMAGUCHI
1st Author's Affiliation Faculty of Engineering Nagaoka University of Technology()
2nd Author's Name Yuuki OOHASHI
2nd Author's Affiliation Faculty of Engineering Nagaoka University of Technology
3rd Author's Name Eichi NAGATOMI
3rd Author's Affiliation Faculty of Engineering Nagaoka University of Technology
4th Author's Name Yasuhiro TAMAYAMA
4th Author's Affiliation Faculty of Engineering Nagaoka University of Technology
5th Author's Name Takahiro KATO
5th Author's Affiliation Faculty of Engineering Nagaoka University of Technology
6th Author's Name Kanji YASUI
6th Author's Affiliation Faculty of Engineering Nagaoka University of Technology
Date 2013-06-21
Paper # EMD2013-22,CPM2013-37,OME2013-45
Volume (vol) vol.113
Number (no) 96
Page pp.pp.-
#Pages 5
Date of Issue