Presentation 2013-05-16
Interface Control of ITO and Polymer Thin Film Using a Reactive SAM
Seong-Ho Kim, Hanae Ohtsuka, Kuniaki Tanaka, Rigoberto C. Advincula, Hiroaki Usui,
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Abstract(in English) The interface between an inorganic electrode and an organic layer plays an important role in determining performances of organic electronic devices. In this work, a reactive self-assembled monolayer (SAM) having benzophenone (BP) terminal was prepared on an indium-tin oxide (ITO) electrode, on which a hole-transport layer of a fluorene-phenoxazine copolymer (H5) was prepared by spin-coating. Subsequent UV irradiation caused to form stable covalent bonds at the interface. It was found that a 6-nm-thick interfacial layer of H5 was stably tethered to the ITO surface. The formation of covalent bonds at the interface contributed to enhance hole injection from ITO to H5 layer. This technique was applied for preparing an organic light emitting diode (OLED), resulting in an improvement of luminescence by covalently tethering the interface between ITO and H5 hole-transport layer.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) self-assembled monolayer / SAM / interface control / ITO / hole-transport layer / OLED
Paper # OME2013-23
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Committee OME
Conference Date 2013/5/9(1days)
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Paper Information
Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Interface Control of ITO and Polymer Thin Film Using a Reactive SAM
Sub Title (in English)
Keyword(1) self-assembled monolayer
Keyword(2) SAM
Keyword(3) interface control
Keyword(4) ITO
Keyword(5) hole-transport layer
Keyword(6) OLED
1st Author's Name Seong-Ho Kim
1st Author's Affiliation Tokyo University of Agriculture and Technology()
2nd Author's Name Hanae Ohtsuka
2nd Author's Affiliation Tokyo University of Agriculture and Technology
3rd Author's Name Kuniaki Tanaka
3rd Author's Affiliation Tokyo University of Agriculture and Technology
4th Author's Name Rigoberto C. Advincula
4th Author's Affiliation Case Western Reserve University
5th Author's Name Hiroaki Usui
5th Author's Affiliation Tokyo University of Agriculture and Technology
Date 2013-05-16
Paper # OME2013-23
Volume (vol) vol.113
Number (no) 42
Page pp.pp.-
#Pages 5
Date of Issue