Presentation | 2013-04-26 Investigation into directional electron transfer of cytochrome c_3 by electrochemical measurement Noriyuki Asakura, Masaki DAGI, Mami Fukai, Naoya SHIBUYA, |
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Abstract(in English) | Cytochrome c_3 is a redox protein containing four hemes in one molecule and works as an electron mediator in vivo. There is intense interest in experiments which reveal, at molecular level, how electrons go into and out of cytochrome c_3. Here we report that specific heme which roles in an entrance or an exit during electron transfer, that is direction of electron transfer through cytochrome c_3, is clarified by electrochemical quartz crystal microbalance (EQCM) measurement. In vivo, cytochrome c_3 accepts/donates electrons from/to hydrogenase, which is catalyze proton reduction and hydrogen oxidation. In this study, electron transfer between cytochrome c_3 and hydrogenase was measured electrochemically, and the electron transfer complex formation was investigated by frequency change of the quartz crystal at the same time as electrochemistry. |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | cytochrome / electron transfer / redox protein / EQCM |
Paper # | SDM2013-18,OME2013-18 |
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Committee | OME |
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Conference Date | 2013/4/18(1days) |
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Registration To | Organic Material Electronics (OME) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | Investigation into directional electron transfer of cytochrome c_3 by electrochemical measurement |
Sub Title (in English) | |
Keyword(1) | cytochrome |
Keyword(2) | electron transfer |
Keyword(3) | redox protein |
Keyword(4) | EQCM |
1st Author's Name | Noriyuki Asakura |
1st Author's Affiliation | Department of Bioengineering, Tokyo Institute of Technology() |
2nd Author's Name | Masaki DAGI |
2nd Author's Affiliation | Department of Bioengineering, Tokyo Institute of Technology |
3rd Author's Name | Mami Fukai |
3rd Author's Affiliation | Department of Bioengineering, Tokyo Institute of Technology |
4th Author's Name | Naoya SHIBUYA |
4th Author's Affiliation | Department of Bioengineering, Tokyo Institute of Technology |
Date | 2013-04-26 |
Paper # | SDM2013-18,OME2013-18 |
Volume (vol) | vol.113 |
Number (no) | 18 |
Page | pp.pp.- |
#Pages | 3 |
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