| Presentation | 2013-04-26 Redox-Active Monolayer on Silicon Surface : Photochemical Attachment of Ferrocene Derivative Molecules and their Electrochemical Behavior Hiroyuki SUGIMURA, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Electrochemically active self-assembled monolayers (SAM) have been successfully attached with atomicscale uniformity on a Si(111) surface by immobilizing vinylferrocene (VFc), ethynylferrocene (EFc) or ferrocenecarboxaldehyde (FcA) molecules through covalent bonds. The reaction of the ferrocene derivatives with the hydrogen-terminated Si (Si(111)-H) surface was photochemically promoted by irradiation of visible light on the Si substrate immersed in n-decane solution of one of the Fc derivatives. We found that aggregation and polymerization was avoided when n-decane was used as a solvent instead of mesitylene. The redox-potentials of the Fc-SAMs were in the order of VFc |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Self-Assembled Monolayer / Silicon / Visible-light excitation / Ferrocene / Redox |
| Paper # | SDM2013-11,OME2013-11 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 2013/4/18(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Redox-Active Monolayer on Silicon Surface : Photochemical Attachment of Ferrocene Derivative Molecules and their Electrochemical Behavior |
| Sub Title (in English) | |
| Keyword(1) | Self-Assembled Monolayer |
| Keyword(2) | Silicon |
| Keyword(3) | Visible-light excitation |
| Keyword(4) | Ferrocene |
| Keyword(5) | Redox |
| 1st Author's Name | Hiroyuki SUGIMURA |
| 1st Author's Affiliation | Department of Materials Science and Engineering, Kyoto University() |
| Date | 2013-04-26 |
| Paper # | SDM2013-11,OME2013-11 |
| Volume (vol) | vol.113 |
| Number (no) | 18 |
| Page | pp.pp.- |
| #Pages | 4 |
| Date of Issue | |