Presentation 2013-03-05
In-situ Scanning Tunneling Microscope Investigation of 2D Self-Assembly of Melem under pH-ControUed Aqueous Solutions
Kenki SAKATA, Masashi AONO, Shinobu UEMURA, Tamikuni KOMATSU, Masashi KUNITAKE,
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Abstract(in English) Self-assembled structures of melem were investigated at aqueous solution-Au(111) interfaces by cyclic voltammetry and in situ scanning tunneling microscopy (STM). In the weakly basic and neutral aqueous solutions of melem, three self-assembled structures, which are a honeycomb network, a close-packed structure and fibril structure, were constructed by electrochemical potential control at the aqueous solution-Au(111) interfaces. In acidic solution, melem formed just honeycomb and close-packed structures. however. such fibril-like structures were not observed because of interruption of heptazine rings stacking between melem molecules by adjacent counter ions.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Self-Assembly / Hydrogen Bond / Solution-Solid Interface / Scanning Tunneling Microscope (STM)
Paper # OME2012-96
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Committee OME
Conference Date 2013/2/26(1days)
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Paper Information
Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) In-situ Scanning Tunneling Microscope Investigation of 2D Self-Assembly of Melem under pH-ControUed Aqueous Solutions
Sub Title (in English)
Keyword(1) Self-Assembly
Keyword(2) Hydrogen Bond
Keyword(3) Solution-Solid Interface
Keyword(4) Scanning Tunneling Microscope (STM)
1st Author's Name Kenki SAKATA
1st Author's Affiliation Graduate School of Science and Technology, Kunamoto University()
2nd Author's Name Masashi AONO
2nd Author's Affiliation Graduate School of Science and Technology, Kunamoto University
3rd Author's Name Shinobu UEMURA
3rd Author's Affiliation Graduate School of Science and Technology, Kunamoto University
4th Author's Name Tamikuni KOMATSU
4th Author's Affiliation High Energy Accelerator Research Organization
5th Author's Name Masashi KUNITAKE
5th Author's Affiliation Graduate School of Science and Technology, Kunamoto University
Date 2013-03-05
Paper # OME2012-96
Volume (vol) vol.112
Number (no) 456
Page pp.pp.-
#Pages 4
Date of Issue