Presentation 2013-03-08
Structural Characterization of 3d Ferromagnetic Transition Metal Thin Films Epitaxially Grown on (100)-Oriented Cubic Single-Crystal Substrates
Mitsuru OHTAKE, Masaaki FUTAMOTO,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Thin films of 3d ferromagnetic transition metals (Fe, Co, and Ni)and teir alloys are prepared on MgO, SrTiO_3,and GaAs single-crystal substrates of (100)orientation. The growth behavior and the structure are investigated by RHEED, XRD, and HR-TEM. Fe, Fe_<65>Co_<35>,Fe_<50>Co_<50>,and Fe_<80>Ni_<20> (at %)films with bcc structure are formed on all the substrates. Co films epitaxially grown on MgO substrates at temperatures higher than 300℃ consist of hcp(1120)bi-crystals, whereas a Co epitaxial film deposited at 100℃ involves an fcc(100)crystal in addition to hcp(1120)crystals. Co_<80>Ni_<20> films grown on MgO substrates consist of a mixture of hcp(1120)and fcc(100)crystals regardless of growth temperature. Ni and Ni_<80>Fe_<20> films grown on MgO substrates include not only fcc(100)but also hcp(1120)crystals which are metastable and stabilized through hetero-epitaxial growth. As the film thickness increases, the Ni and the Ni_<80>Fe_<20> crystals of hcp(1120)orientation tend to transform into more stable fee crystals of (110)orientation by atomic displacement parallel to the hcp(0001)close-packed plane. Co, Co_<80>Ni_<20>,Ni, and Ni_<80>Fe_<20> films with fee strueture grow epitaxially on SrTiO_3 substrates. Metastable bcc crystals nucleate i early stages of Co, Ni, and Ni_<80>Fe_<20> film growth on GaAs substrates. With increasing the thickness, the metastable bcc structure starts to transform into fee strueture through atomic displacement parallel to the bcc{110} close-packed planes. XRD indicates that the strains in films epitaxially grown on MgO substrates are very small though the lattice mismatches are as large as 3-17%. Cross-sectional HR-TEM shows that a lot of misfit dislocations are introduced in the films around film/substrate interfaces to reduce the mismatches.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Fe / Co / Ni / Fe-Co / Co-Ni / Ni-Fe / thin film / epitaxial growth / crystal structure / stable phase / metastable phase
Paper # MR2012-51
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Committee MR
Conference Date 2013/3/1(1days)
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Paper Information
Registration To Magnetic Recording (MR)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Structural Characterization of 3d Ferromagnetic Transition Metal Thin Films Epitaxially Grown on (100)-Oriented Cubic Single-Crystal Substrates
Sub Title (in English)
Keyword(1) Fe
Keyword(2) Co
Keyword(3) Ni
Keyword(4) Fe-Co
Keyword(5) Co-Ni
Keyword(6) Ni-Fe
Keyword(7) thin film
Keyword(8) epitaxial growth
Keyword(9) crystal structure
Keyword(10) stable phase
Keyword(11) metastable phase
1st Author's Name Mitsuru OHTAKE
1st Author's Affiliation Faculty of Science and Engineering, Chuo University()
2nd Author's Name Masaaki FUTAMOTO
2nd Author's Affiliation Faculty of Science and Engineering, Chuo University
Date 2013-03-08
Paper # MR2012-51
Volume (vol) vol.112
Number (no) 452
Page pp.pp.-
#Pages 6
Date of Issue