Presentation 2010-04-23
Synthesis and optoelectronic properties of soluble core-shell hybrids having polythiophene core
Hiroshi OYA, Ken TAKANO, Hideharu MORI,
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Abstract(in English) Polythiophene exhibits excellent optoelectronic properties with a wide variety of possible applications, such as organic electroluminescence materials, organic transistors, and sensors. In this study, amphiphilic block copolymers having cross-linkable segments were synthesized by RAFT(Reversible Addition-Fragmentation Chain Transfer)polymerization of 2,5-dibromo- 3-vinylthiophene(DB3VT). For the production of novel polythiophene-based nanomaterials, we attempted the formation of highly ordered structures by self-assembly of the amphiphilic block copolymers in selective solvent, followed by coupling reaction of the bromine moieties in the poly(DB3VT)segment. Resulting core-shell hybrids having polythiophene core were characterized by dynamic light scattering(DLS), UV-vis, and fluorescence spectroscopic methods.
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Keyword(in English) Polythiophene / Core-shell hybrid / Amphiphilic block copolymer / Self-assembly
Paper # ED2010-10
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Committee ED
Conference Date 2010/4/15(1days)
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Language JPN
Title (in Japanese) (See Japanese page)
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Title (in English) Synthesis and optoelectronic properties of soluble core-shell hybrids having polythiophene core
Sub Title (in English)
Keyword(1) Polythiophene
Keyword(2) Core-shell hybrid
Keyword(3) Amphiphilic block copolymer
Keyword(4) Self-assembly
1st Author's Name Hiroshi OYA
1st Author's Affiliation Department of Polymer Science and Engineering, Yamagata University()
2nd Author's Name Ken TAKANO
2nd Author's Affiliation Department of Polymer Science and Engineering, Yamagata University
3rd Author's Name Hideharu MORI
3rd Author's Affiliation Department of Polymer Science and Engineering, Yamagata University
Date 2010-04-23
Paper # ED2010-10
Volume (vol) vol.110
Number (no) 11
Page pp.pp.-
#Pages 5
Date of Issue