Presentation 2008-10-31
Relation between Debye temperature measured by ultrasonic method and heat capacity of oxide glasses
Seiji Inaba, Shigeru Fujino, Yasuya Nakayama, Toshihisa Kajiwara,
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Abstract(in English) Some binary and ternary silicate, aluminosilicate, borate, phosphate, tellurite, gerumanate and heavy metal oxide glasses were prepared in melting method. Debye temperature was calculated form mean velocity measured by ultrasonic method. Heat capacity was measured in the temperature range from 300 to 840K by A.C. calorimetry. We proposed an empirical equation for estimating the mean velocity in terms of ionic packing ratio and dissociation energy of oxide glass. The relationship between heat capacity and chemical composition was discussed by use of the Debye model. We found that heat capacities of all the samples studied here scaled with the molar heat capacity at the Debye temperature have a similar magnitude and temperature dependence, from 300K to the glass transition points. Based on the observation obtained in this work, we proposed an empirical equation which is composed of Debye temperature calculated form chemical composition.
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Keyword(in English) Oxide glass / composition / ultrasonic method / velocity / Debye temperature / A.C. calorimetry / heat capacity
Paper # US2008-58
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Conference Date 2008/10/23(1days)
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Language JPN
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Title (in English) Relation between Debye temperature measured by ultrasonic method and heat capacity of oxide glasses
Sub Title (in English)
Keyword(1) Oxide glass
Keyword(2) composition
Keyword(3) ultrasonic method
Keyword(4) velocity
Keyword(5) Debye temperature
Keyword(6) A.C. calorimetry
Keyword(7) heat capacity
1st Author's Name Seiji Inaba
1st Author's Affiliation Faculty of Engineering, Kyushu University()
2nd Author's Name Shigeru Fujino
2nd Author's Affiliation Faculty of Engineering, Kyushu University
3rd Author's Name Yasuya Nakayama
3rd Author's Affiliation Faculty of Engineering, Kyushu University
4th Author's Name Toshihisa Kajiwara
4th Author's Affiliation Faculty of Engineering, Kyushu University
Date 2008-10-31
Paper # US2008-58
Volume (vol) vol.108
Number (no) 266
Page pp.pp.-
#Pages 5
Date of Issue