Presentation 2008-06-27
Supramolecular Aggregation of Gold Nanoparticles by Potential-Controlled Adsorption
Shin-ichiro NAKAJIMA, Kazuhiko YAMADA, Ken ONISHI,
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Abstract(in English) Recent work on gold nanoparticles has flourished in the past few years, as a result of development of several methods to control the particle size and to stabilize the particles in solution. More, considerable attention focuses on the possibility of nanoparticles assembly because of their important physical, electronic, optical properties, and of potential applications for electronic circuit components of extraordinary high integration. Among various patterning strategies have been developed to create characteristic ordered nanostructures of gold nanoparticles, herein we report a new methodology for a reversible self-assembly of gold nanoparticles bearing β-cyclodextrins, which was constructed by potential-controlled adsorption onto Au(111) surfaces in sodium perchrolate solution. The gold nanoparticles adsorb randomly on Au(111) at a positive potential of more than 0V vs. SCE. On the other hand, a cohesive structure of the particles is observed at the range of a potential from -0.6 to 0V vs. SCE, due mainly to weaken adsorption of the particles, resulting intermolecular interaction of the β-cyclodextrin substituted onto the gold nanoparticles.
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Keyword(in English) Gold nanoparticles / Cyclodextrin / Ordered nanostructure / Self-assembly / Adsorption
Paper # EMD2008-14,CPM2008-33,OME2008-35
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Committee OME
Conference Date 2008/6/20(1days)
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Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Supramolecular Aggregation of Gold Nanoparticles by Potential-Controlled Adsorption
Sub Title (in English)
Keyword(1) Gold nanoparticles
Keyword(2) Cyclodextrin
Keyword(3) Ordered nanostructure
Keyword(4) Self-assembly
Keyword(5) Adsorption
1st Author's Name Shin-ichiro NAKAJIMA
1st Author's Affiliation Central Research Laboratory, Japan Aviation Electronics Industry, Ltd.()
2nd Author's Name Kazuhiko YAMADA
2nd Author's Affiliation Central Research Laboratory, Japan Aviation Electronics Industry, Ltd.
3rd Author's Name Ken ONISHI
3rd Author's Affiliation Central Research Laboratory, Japan Aviation Electronics Industry, Ltd.
Date 2008-06-27
Paper # EMD2008-14,CPM2008-33,OME2008-35
Volume (vol) vol.108
Number (no) 112
Page pp.pp.-
#Pages 6
Date of Issue