Presentation 2008-03-03
Scanning Tunneling Spectroscopy Mapping of a Single Lu@C_<82> on Alkanethiol Self Assembled Monolayer
Yuhsuke YASUTAKE, Keijiro KONO, Masachika IWAMOTO, Norihiro KOBAYASHI, Hisashi UMEMOTO, Yasuhiro ITO, Haruya OKIMOTO, Hisanori SHINOHARA, Yutaka MAJIMA,
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Abstract(in English) Endohedral metallofullerenes have electric dipole moment due to the exchange of electrons between the encapsulated metal atom and a fullerene cage. To realize molecular switching devices using an endohedral metallofullerene, it is important to characterize the local electrical properties of single endohedral metallofullerene. Here, we demonstrate the local electrical properties of Lu@C_<82> molecule on alkanethiol SAM by scanning tunneling spectroscopy (STS) mapping. From differential conductance spectra, we observe HOMO peak intensity of Lu@C_<82> shows a spatial dependence. We discuss the relationship between the molecular orientation and the spatial dependence of HOMO peak intensity.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Scanning Tunneling Microscopy / Scanning Tunneling Spectroscopy / Endohedral Metallofullerene / Self Assembled Monolayer
Paper # EID2007-106,OME2007-88
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Committee EID
Conference Date 2008/2/25(1days)
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Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Scanning Tunneling Spectroscopy Mapping of a Single Lu@C_<82> on Alkanethiol Self Assembled Monolayer
Sub Title (in English)
Keyword(1) Scanning Tunneling Microscopy
Keyword(2) Scanning Tunneling Spectroscopy
Keyword(3) Endohedral Metallofullerene
Keyword(4) Self Assembled Monolayer
1st Author's Name Yuhsuke YASUTAKE
1st Author's Affiliation Department of Physical Electronics, Tokyo Institute of Technology()
2nd Author's Name Keijiro KONO
2nd Author's Affiliation Department of Physical Electronics, Tokyo Institute of Technology
3rd Author's Name Masachika IWAMOTO
3rd Author's Affiliation Department of Physical Electronics, Tokyo Institute of Technology
4th Author's Name Norihiro KOBAYASHI
4th Author's Affiliation Department of Physical Electronics, Tokyo Institute of Technology
5th Author's Name Hisashi UMEMOTO
5th Author's Affiliation Department of Chemistry & Institute for Advanced Research Nagoya University
6th Author's Name Yasuhiro ITO
6th Author's Affiliation Department of Chemistry & Institute for Advanced Research Nagoya University
7th Author's Name Haruya OKIMOTO
7th Author's Affiliation Department of Chemistry & Institute for Advanced Research Nagoya University
8th Author's Name Hisanori SHINOHARA
8th Author's Affiliation Department of Chemistry & Institute for Advanced Research Nagoya University
9th Author's Name Yutaka MAJIMA
9th Author's Affiliation Department of Physical Electronics, Tokyo Institute of Technology
Date 2008-03-03
Paper # EID2007-106,OME2007-88
Volume (vol) vol.107
Number (no) 521
Page pp.pp.-
#Pages 6
Date of Issue