Presentation 2007-06-29
Holographic Memory Materials Based on Stepwise Two-photon Absorption
Yuhei MORI, Hirohisa KANBARA, Katsuhiko HIRABAYASHI, Takashi KURIHARA, Masaki SHIMIZU, Tamejiro HIYAMA,
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Abstract(in English) For the holographic recording system of the stepwise two-photon absorption process, the dependence of the holographic efficiency upon the dispersing binder polymer has been measured. In the recording film, the two-photon absorption material is oligothiophene and the energy acceptor is aryl azide. Various films have been prepared by changing the dispersing polymer, where the final reaction occurs, among zeonex, PMMA and photopolymer. The film with the photopolymer has the highest holographic efficiency among the three. It has been found that photopolymer works effectively even for the stepwise two-photon holographic process in addition to the ordinary one-photon process. The energy accepter molecule has been changed from aryl azide into several aryl ketone molecules. The holographic efficiency, the reactivity and the triplet excited states for the molecules are investigated.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Oligothiophene / Azide / Holographic Memory / Triplet / Density Functional Theory / Photopolymer
Paper # EMD2007-12,CPM2007-30,OME2007-16
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Conference Information
Committee EMD
Conference Date 2007/6/22(1days)
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Registration To Electromechanical Devices (EMD)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Holographic Memory Materials Based on Stepwise Two-photon Absorption
Sub Title (in English)
Keyword(1) Oligothiophene
Keyword(2) Azide
Keyword(3) Holographic Memory
Keyword(4) Triplet
Keyword(5) Density Functional Theory
Keyword(6) Photopolymer
1st Author's Name Yuhei MORI
1st Author's Affiliation NTT Photonics Laboratories()
2nd Author's Name Hirohisa KANBARA
2nd Author's Affiliation NTT Photonics Laboratories
3rd Author's Name Katsuhiko HIRABAYASHI
3rd Author's Affiliation NTT Photonics Laboratories
4th Author's Name Takashi KURIHARA
4th Author's Affiliation NTT Photonics Laboratories:Kyoto University International Innovation Center
5th Author's Name Masaki SHIMIZU
5th Author's Affiliation Department of Material Chemistry, Faculty of Engineering, Kyoto University
6th Author's Name Tamejiro HIYAMA
6th Author's Affiliation Department of Material Chemistry, Faculty of Engineering, Kyoto University
Date 2007-06-29
Paper # EMD2007-12,CPM2007-30,OME2007-16
Volume (vol) vol.107
Number (no) 121
Page pp.pp.-
#Pages 6
Date of Issue