Presentation 2007/1/18
Multibubble-Sonoluminescence and Na-atom Emission from NaCl Solutions
Shogo ABE, Yuichi HAYASHI, Pak-Kon CHOI,
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Abstract(in English) We have measured the spectra of multi-bubble sonoluminescence from Ar-saturated NaCl solutions at the frequencies of 108kHz and 1.0MHz. The intensity of sodium-atom emission observed takes a maximum at the concentration of 2M, which corresponds to the formation of OH radicals measured using KI colorimetric method. High-resolution spectroscopic study was made on sodium D lines for various ultrasonic powers. The effects of ethanol on the sodium D line-width were also investigated. The line-width showed asymmetric broadening toward red region, and depended on the ultrasonic power. The addition of ethanol in the range of 0.5-2mM caused sudden quenching and broadening of sodium D lines. The results indicate that collisions between excited sodium atoms and foreign atoms, that is, argon gas and molecules decomposed from ethanol are responsible for the observed line broadening. This clearly demonstrates that the sodium-atom emission occurs within bubbles. The electronic exciting process of sodium atom is discussed in terms of chemical excitation by OH radicals or H radicals.
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Keyword(in English) NaCl / sonoluminescence / sodium D lines / OH radicals / line broadening / ethanol
Paper # US2006-95
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Committee US
Conference Date 2007/1/18(1days)
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Registration To Ultrasonics (US)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Multibubble-Sonoluminescence and Na-atom Emission from NaCl Solutions
Sub Title (in English)
Keyword(1) NaCl
Keyword(2) sonoluminescence
Keyword(3) sodium D lines
Keyword(4) OH radicals
Keyword(5) line broadening
Keyword(6) ethanol
1st Author's Name Shogo ABE
1st Author's Affiliation Department of Physics, Meiji University()
2nd Author's Name Yuichi HAYASHI
2nd Author's Affiliation Department of Physics, Meiji University
3rd Author's Name Pak-Kon CHOI
3rd Author's Affiliation Department of Physics, Meiji University
Date 2007/1/18
Paper # US2006-95
Volume (vol) vol.106
Number (no) 481
Page pp.pp.-
#Pages 6
Date of Issue