Presentation 2006/6/26
Investigation of Growth Process of Carbon Nanotubes on Cobalt Catalysts using Infrared Absorption Spectroscopy(Session 8B Emerging Devices and Technologies II)
Yasuo Kimura, Takeru Numasawa, Mizuhisa Nihei, Michio Niwano,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) We have in-situ observed infrared absorption spectra for cobalt catalyst surface during growing carbon nanotubes by the thermal chemical vapor deposition method to elucidate the growth mechanism of CNT on cobalt catalysts. CH_3OH and CH_4 gases were used as a source. CNT grew when CH_3OH gas was used while it did not grow when CH_4 gas was used. We observed two peaks due to oxygen adsorbed on cobalt surface and CoOCH_3 species when CNT was grown. The infrared absorption spectral changes indicate that the CoO-C bond plays an important role in the CNT growth mechanism on cobalt catalysts and infrared absorption spectroscopy is capable of sensitive analysis of the chemical reaction on cobalt catalysts.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) CNT / oxygen / cobalt / catalyst / in-situ / infrared absorption spectroscopy
Paper # ED2006-108,SDM2006-116
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Committee SDM
Conference Date 2006/6/26(1days)
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Registration To Silicon Device and Materials (SDM)
Language ENG
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Investigation of Growth Process of Carbon Nanotubes on Cobalt Catalysts using Infrared Absorption Spectroscopy(Session 8B Emerging Devices and Technologies II)
Sub Title (in English)
Keyword(1) CNT
Keyword(2) oxygen
Keyword(3) cobalt
Keyword(4) catalyst
Keyword(5) in-situ
Keyword(6) infrared absorption spectroscopy
1st Author's Name Yasuo Kimura
1st Author's Affiliation Research Institute of Electrical Communication (RIEC), Tohoku University:Core Research for Evolutional Science and Technology (CREST)()
2nd Author's Name Takeru Numasawa
2nd Author's Affiliation Research Institute of Electrical Communication (RIEC), Tohoku University
3rd Author's Name Mizuhisa Nihei
3rd Author's Affiliation Fujitsu Laboratories Ltd.
4th Author's Name Michio Niwano
4th Author's Affiliation Research Institute of Electrical Communication (RIEC), Tohoku University:Core Research for Evolutional Science and Technology (CREST)
Date 2006/6/26
Paper # ED2006-108,SDM2006-116
Volume (vol) vol.106
Number (no) 138
Page pp.pp.-
#Pages 3
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