| Presentation | 2006-06-30 Structure analysis of deposition polymerized thin film by in situ IR spectroscopy Kenji NAKAO, Kuniaki TANAKA, Hiroaki USUI, |
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| PDF Download Page |  PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Polymeric thin films were obtained by electron-assisted deposition of zinc acrylate (ZA) and fluorinated alkyl acrylate (EFUA) monomers. The film growth process and thermal stability of the films were analyzed by using in-situ IR analysis. It was found that the polymerization reaction can be enhanced by electron irradiation in the course of deposition. The polymerization was achieved from the initial stage of film growth. The electron-assisted deposition of ZA produced polymeric films that was not affected by post-deposition annealing in vacuum. On the other hand, the conventionally evaporated ZA film underwent solid phase polymerization and reevaporation by the post-deposition annealing. EFUA polymer films were prepared by the electron-assisted deposition only when the substrate temperature was cooled to subfreezing temperature, while co-evaporation of ZA and EFUA enabled formation of polymer films without cooling the substrate. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | deposition polymerization / co-deposition / zinc-acrylate / fluoro-alkyl acrylate / in-situ IR analysis |
| Paper # | EMD2006-5,CPM2006-29,OME2006-39 |
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| Conference Information | |
| Committee | CPM |
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| Conference Date | 2006/6/23(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Vice Chair | |
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| Paper Information | |
| Registration To | Component Parts and Materials (CPM) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Structure analysis of deposition polymerized thin film by in situ IR spectroscopy |
| Sub Title (in English) | |
| Keyword(1) | deposition polymerization |
| Keyword(2) | co-deposition |
| Keyword(3) | zinc-acrylate |
| Keyword(4) | fluoro-alkyl acrylate |
| Keyword(5) | in-situ IR analysis |
| 1st Author's Name | Kenji NAKAO |
| 1st Author's Affiliation | Faculty of Engineering, Tokyo University of Agriculture & Technology() |
| 2nd Author's Name | Kuniaki TANAKA |
| 2nd Author's Affiliation | Faculty of Engineering, Tokyo University of Agriculture & Technology |
| 3rd Author's Name | Hiroaki USUI |
| 3rd Author's Affiliation | Faculty of Engineering, Tokyo University of Agriculture & Technology |
| Date | 2006-06-30 |
| Paper # | EMD2006-5,CPM2006-29,OME2006-39 |
| Volume (vol) | vol.106 |
| Number (no) | 131 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |