Presentation 2005/8/26
A Combination of Dye Molecules for Blue, Green and Red Emissions in Polysilane-Based Electroluminescent Devices
Akira MATSUMOTO, Takahiro IGA, Kentaro OJIMA, Norihiko KAMATA, Ken HATANO, Daiyo TERUNUMA,
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Abstract(in English) Polysilanes have high excitonic emission efficiency in UV region as well as one-dimensional conductivity. We realized the first polysilane-based electroluminescence in wide visible-wavelength range by utilizing an efficient resonant-energy transfer to energy-matched organic dye molecules in their spin-coated mixed films. The method has a fundamental advantage of controlling blue (B), green (G) and red (R) components in the spectrum simply by mixing dye molecules in solution. In practice, however, detailed consideration on the energy transfer among dye molecules was necessary in the previous combination. Here we propose another combination of TPB, coumarin 6 and Eu complex for an energy donor of polymethylphenylsilane (PMPS). An independent control of B and R became possible owing to no overlap in energy between TPB and Eu complex. The energy of G emission comes from the energy transfer from TPB, but high solubility of TPB makes it possible to control G/B ratio easily also. The combination, therefore, improved the controllability of the EL spectrum and the purity of white emission based on PMPS.
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Keyword(in English) Polysilane / Wet Process / Electroluminescence / Resonant Energy Transfer
Paper # ED2005-115,OME2005-41
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Committee OME
Conference Date 2005/8/26(1days)
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Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) A Combination of Dye Molecules for Blue, Green and Red Emissions in Polysilane-Based Electroluminescent Devices
Sub Title (in English)
Keyword(1) Polysilane
Keyword(2) Wet Process
Keyword(3) Electroluminescence
Keyword(4) Resonant Energy Transfer
1st Author's Name Akira MATSUMOTO
1st Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University()
2nd Author's Name Takahiro IGA
2nd Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University
3rd Author's Name Kentaro OJIMA
3rd Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University
4th Author's Name Norihiko KAMATA
4th Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University
5th Author's Name Ken HATANO
5th Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University
6th Author's Name Daiyo TERUNUMA
6th Author's Affiliation Department of Functional Materials Science, Faculty of Engineering, Saitama University
Date 2005/8/26
Paper # ED2005-115,OME2005-41
Volume (vol) vol.105
Number (no) 258
Page pp.pp.-
#Pages 5
Date of Issue