Presentation | 2005/1/21 in situ Polymerization of Conducting Polymers : A Consideration of the Nature of Substrate Surface and Deposition Process Mitsuyoshi Onoda, Kazuya Tada, |
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Abstract(in English) | The surface treatment of glass substrates affects the in situ polymerization of pyrrole on them. Here, we have studied the initial deposition process for the positively charged substrates. It was found that no notable difference is induced by dipping the substrates in solutions containing one or two components of the in situ polymerization solution, prior to in situ polymerization. However, dipping in the in situ polymerization solution containing all three components, pyrrole, FeCl_3 and p-toluenesolfonic acid sodium salt (p-TSNa) removed the rest time. This fact implies that the polymerization reaction of pyrrole on the substrate is required to initiate the deposition of polypyrrole. It was also observed that photoelectron emission from the substrates for which the polymerization was quenched during the rest time, indicating the depositon of oligomerized or polymerized pyrrole on the substrates although the deposition could not be detected by the optical absorption spectra. |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | conducting polymer / in situ polymerization / polypyrrole / molecular selfassembly techniques |
Paper # | OME2004-126 |
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Committee | OME |
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Conference Date | 2005/1/21(1days) |
Place (in Japanese) | (See Japanese page) |
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Registration To | Organic Material Electronics (OME) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | in situ Polymerization of Conducting Polymers : A Consideration of the Nature of Substrate Surface and Deposition Process |
Sub Title (in English) | |
Keyword(1) | conducting polymer |
Keyword(2) | in situ polymerization |
Keyword(3) | polypyrrole |
Keyword(4) | molecular selfassembly techniques |
1st Author's Name | Mitsuyoshi Onoda |
1st Author's Affiliation | Department of Electrical Engineering and Computer Sciences, Graduate School of Engineering University of Hyogo() |
2nd Author's Name | Kazuya Tada |
2nd Author's Affiliation | Department of Electrical Engineering and Computer Sciences, Graduate School of Engineering University of Hyogo |
Date | 2005/1/21 |
Paper # | OME2004-126 |
Volume (vol) | vol.104 |
Number (no) | 641 |
Page | pp.pp.- |
#Pages | 4 |
Date of Issue |