Presentation | 2005/1/21 Preparation of polymer thin films by physical vapor deposition combined with SAM Kiyoi KATSUKI, Kuniaki TANAKA, Akira KAWAKAMI, Rigoberto ADVINCULA, Hiroaki USUI, |
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Abstract(in Japanese) | (See Japanese page) |
Abstract(in English) | A new film formation method was developed that can form polymer thin films chemically bound to substrate surface by combining the physical vapor deposition and self-assembled monolayer (SAM). A SAM layer of azo-initiator (VAZO56) was formed on Au surface, on which 3-(N-carbazolyl)propyl acrylate monomer was evaporated. The initiator was activated by UV irradiation after the deposition to obtain chemically bound vinyl polymer thin films having carbazole pendant groups. While the simply evaporated film suffered crystallization, the combination of SAM and deposition polymerization was effective in improving the surface smoothness, thermal stability, and film-substrate adhesion as a consequence of the formation of covalent chemical bonds between the film and the substrate. |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | Physical vapor deposition / Self-assembled Monolayer / Deposition polymerization / Carbazole |
Paper # | OME2004-125 |
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Committee | OME |
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Conference Date | 2005/1/21(1days) |
Place (in Japanese) | (See Japanese page) |
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Registration To | Organic Material Electronics (OME) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | Preparation of polymer thin films by physical vapor deposition combined with SAM |
Sub Title (in English) | |
Keyword(1) | Physical vapor deposition |
Keyword(2) | Self-assembled Monolayer |
Keyword(3) | Deposition polymerization |
Keyword(4) | Carbazole |
1st Author's Name | Kiyoi KATSUKI |
1st Author's Affiliation | Tokyo University of Agriculture and Technology() |
2nd Author's Name | Kuniaki TANAKA |
2nd Author's Affiliation | Tokyo University of Agriculture and Technology |
3rd Author's Name | Akira KAWAKAMI |
3rd Author's Affiliation | TRADIM |
4th Author's Name | Rigoberto ADVINCULA |
4th Author's Affiliation | University of Houston |
5th Author's Name | Hiroaki USUI |
5th Author's Affiliation | Tokyo University of Agriculture and Technology |
Date | 2005/1/21 |
Paper # | OME2004-125 |
Volume (vol) | vol.104 |
Number (no) | 641 |
Page | pp.pp.- |
#Pages | 4 |
Date of Issue |