Presentation 2005/3/4
Analysis on Enhanced Crystallization of Oxide Thin Films Caused by Prebaking under Reduced Oxygen Ambience
Yoshihisa FUJISAKI, Hiroshi ISHIWARA,
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Abstract(in English) The ferroelectricity of sol-gel derived 80-nm Bi_<3.45>La_<0.75>Ti_3O_<12> (BLT) films was found to be significantly enhanced by low-pressure baking during the sol-gel process. The ferroelectricity enhancement was caused by the low-pressure baking after the drying process in air and before the crystallization of the dried gel. The maximum remanent polarization (Pr) was 27.2 μC/cm^2, which was achieved after baking at 1.3 kPa oxygen pressure. The coercive field of 54.3 kV/cm was also achieved at the same time. This Pr value is 2.3 times larger than the value attainable with the usual 1-atm baking process. The saturation property of the same capacitor proved that +/-1.2 V operation is possible. The crystal graphical analysis mainly on the structure of dried gels was carried out to investigate the mechanism of large ferroelectricity enhancements. As a result, the porous structure of the gel dried under the low pressure oxygen ambience is found to be attributable to this enhancements.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) BLT / ferroelectricity / sol-gel / low pressure baking
Paper # SDM2004-255
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Conference Information
Committee SDM
Conference Date 2005/3/4(1days)
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Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Analysis on Enhanced Crystallization of Oxide Thin Films Caused by Prebaking under Reduced Oxygen Ambience
Sub Title (in English)
Keyword(1) BLT
Keyword(2) ferroelectricity
Keyword(3) sol-gel
Keyword(4) low pressure baking
1st Author's Name Yoshihisa FUJISAKI
1st Author's Affiliation Central Research Laboratory, Hitachi Ltd.()
2nd Author's Name Hiroshi ISHIWARA
2nd Author's Affiliation Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
Date 2005/3/4
Paper # SDM2004-255
Volume (vol) vol.104
Number (no) 713
Page pp.pp.-
#Pages 6
Date of Issue