| Presentation | 2005/4/14 Molecular Arrangement of Oriented Polymer Films by Friction-Transfer Technique Shuichi NAGAMATSU, Masahiro MISAKI, Yuji YOSHIDA, Nobutaka TANIGAKI, Kiyoshi YASE, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | A one of the polyphenylenevinylene derivatives, poly(2,5-bisoctyloxy-1,4-phenylenevinylene (BOPPV), was found to form highly oriented film by a friction-transfer technique. The polarized absorption spectra of the friction-deposited BOPPV film show strong dichroism with a dichroic ratio of ca. 8 in the drawing direction of friction-transfer. Also, the polarized photoluminescence spectra show strong anisotropy with a dichroic ratio of ca.18. BOPPV molecules in friction-deposited film are highly aligned along the drawing direction of friction-transfer. The feature information of molecular arrangement in the friction-deposited BOPPV film was investigated by both out-of-plane and in-plane X-ray diffraction (XRD) analyses. XRD measurements show that side-chains lie in the film plane, and the polymer backbones are well-ordered along the drawing direction of friction-transfer in the film plane. The polymer backbones form a layered structure with the stacking of molecular plane normal to the film surface. The polymer molecules in the friction-deposited films are ideally arranged three-dimensionally. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | molecular arrangement / polyphenylenevinylene / friction-transfer technique / polarized spectroscopy / X-ray diffraction |
| Paper # | ED2005-6,SDM2005-6,OME2005-6 |
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| Conference Information | |
| Committee | ED |
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| Conference Date | 2005/4/14(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Electron Devices (ED) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Molecular Arrangement of Oriented Polymer Films by Friction-Transfer Technique |
| Sub Title (in English) | |
| Keyword(1) | molecular arrangement |
| Keyword(2) | polyphenylenevinylene |
| Keyword(3) | friction-transfer technique |
| Keyword(4) | polarized spectroscopy |
| Keyword(5) | X-ray diffraction |
| 1st Author's Name | Shuichi NAGAMATSU |
| 1st Author's Affiliation | Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST)() |
| 2nd Author's Name | Masahiro MISAKI |
| 2nd Author's Affiliation | Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) |
| 3rd Author's Name | Yuji YOSHIDA |
| 3rd Author's Affiliation | Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) |
| 4th Author's Name | Nobutaka TANIGAKI |
| 4th Author's Affiliation | Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) |
| 5th Author's Name | Kiyoshi YASE |
| 5th Author's Affiliation | Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST) |
| Date | 2005/4/14 |
| Paper # | ED2005-6,SDM2005-6,OME2005-6 |
| Volume (vol) | vol.105 |
| Number (no) | 18 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |