| Presentation | 2005/4/14 Characteristic Features of Molecular Structure and Packing of Organopolysilanes with Asymmetric Side-Chains Shoji FURUKAWA, Hidetaka OHTA, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | We have studied molecular structure and packing of various silicon-based polymers with symmetric and asymmetric side-chains, such as, poly(di-methyl silane), poly(di-ethyl silane), poly(di-n-propyl silane), poly(di-n-butyl silane), poly(di-n-pentyl silane), poly(di-n-hexyl silane), poly(methyl ethyl silane), and poly(methyl n-propyl silane). As a result, it is found that the two side-chains bonded to a silicon atom stretch asymmetrically due to the intra-molecular steric hindrance even organopolysilanes with symmetric side-chains. These side-chains are bonded to the adjacent side-chains bonded to the second nearest-neighbor silicon atoms by van der Waals force. In this paper, molecular structure and packing of various organopolysilanes with asymmetric side-chains are examined by X-ray diffraction method. Difference and similarity between organopolysilanes with symmetric and asymmetric side-chains are discussed on the bases of the obtained structures. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Organopolysilane / Asymmetric Side-Chain / Molecular Structure / Packing / van der Waals Force |
| Paper # | ED2005-1,SDM2005-1,OME2005-1 |
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| Conference Information | |
| Committee | ED |
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| Conference Date | 2005/4/14(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Electron Devices (ED) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Characteristic Features of Molecular Structure and Packing of Organopolysilanes with Asymmetric Side-Chains |
| Sub Title (in English) | |
| Keyword(1) | Organopolysilane |
| Keyword(2) | Asymmetric Side-Chain |
| Keyword(3) | Molecular Structure |
| Keyword(4) | Packing |
| Keyword(5) | van der Waals Force |
| 1st Author's Name | Shoji FURUKAWA |
| 1st Author's Affiliation | Graduate School of Computer Science and Systems Engineering Kyushu Institute of Technology() |
| 2nd Author's Name | Hidetaka OHTA |
| 2nd Author's Affiliation | Graduate School of Computer Science and Systems Engineering Kyushu Institute of Technology |
| Date | 2005/4/14 |
| Paper # | ED2005-1,SDM2005-1,OME2005-1 |
| Volume (vol) | vol.105 |
| Number (no) | 18 |
| Page | pp.pp.- |
| #Pages | 5 |
| Date of Issue | |