Presentation 2004/11/4
Preparation and annealing effect of Cu-Al-O films by the facing targets spattering method
Junya OGATA, Yuji ITOH, Nozomu TUBOI, Satoshi KOBAYASHI, Hidehiko SHIMIZU, Keizou KATOH, Futao KANEKO,
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Abstract(in English) Cu-Al-O films were deposited at 700℃ by using dc-reactive sputtering with Cu and Al elemental targets under Ar-diluted oxygen gas (O_2: 5~20%) atmosphere, and then annealed at 1050℃ in nitrogen atmosphere. Regardless of the gas ratio of O_2 to Ar, the molar fraction of oxygen in as-deposited films was around 0.6. All as-deposited films exhibited XRD lines of CuAl_2O_4 and CuO. The annealing process caused the molar fraction of oxygen to approach 0.5, resulting in disappearance of the CuAl_2O_4 XRD lines. The annealed films with [Cu]/[Al]~1, exhibiting intense CuAlO_2 XRD lines and the weak CuO XRD line, had the absorption edge corresponding to the energy gap of CuAlO_2 and p-type conductivity. This indicates that the annealed films with [Cu]/[Al]-1 are dominated by CuAlO_2 phase.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) CuAlO_2 films / delafossite structure / reactive spattering / transparent conducting oxide
Paper # CPM2004-132
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Committee CPM
Conference Date 2004/11/4(1days)
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Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Preparation and annealing effect of Cu-Al-O films by the facing targets spattering method
Sub Title (in English)
Keyword(1) CuAlO_2 films
Keyword(2) delafossite structure
Keyword(3) reactive spattering
Keyword(4) transparent conducting oxide
1st Author's Name Junya OGATA
1st Author's Affiliation Graduate School of Science and Technology, Niigata University()
2nd Author's Name Yuji ITOH
2nd Author's Affiliation Graduate School of Science and Technology, Niigata University
3rd Author's Name Nozomu TUBOI
3rd Author's Affiliation Center for Transdisciplinaty Research, Niigata University:Faculty of Engineering, Niigata University
4th Author's Name Satoshi KOBAYASHI
4th Author's Affiliation Faculty of Engineering, Niigata University
5th Author's Name Hidehiko SHIMIZU
5th Author's Affiliation Center for Transdisciplinaty Research, Niigata University:Faculty of Engineering, Niigata University
6th Author's Name Keizou KATOH
6th Author's Affiliation Center for Transdisciplinaty Research, Niigata University:Graduate School of Science and Technology, Niigata University
7th Author's Name Futao KANEKO
7th Author's Affiliation Center for Transdisciplinaty Research, Niigata University:Faculty of Engineering, Niigata University
Date 2004/11/4
Paper # CPM2004-132
Volume (vol) vol.104
Number (no) 425
Page pp.pp.-
#Pages 5
Date of Issue