Presentation 2005/5/6
Charactarization of Nanocrystalline Silicon using Photoacoustic Method
Masashi INOGUCHI, Qing Shen, Taro TOYODA,
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Abstract(in English) We applied a photoacoustic (PA) technique to study the optical absorption and thermal diffusivity of nanocrystalline silicon (NSi) samples. The NSi layers were formed on p-type Si wafers in an HF electrolyte. Three kinds of NSi samples that had undergone chemical post-etching were studied before and after UV irradiation for 2 h. We observed that a strong confinement effect occurred in all of the NSi samples from the blue shift of the band gap energy compared with that of crystalline Si, while the effective thermal diffusivities were almost two orders of the magnitude smaller than that of conventional Si crystals. The band gap shifted to higher energy and the effective thermal diffusivity decreased as the post-etching time increased. In the case of a NSi sample that was not chemically post-etched, the optical absorption and effective thermal diffusivity before and after UV irradiation were almost unchanged. However, for the NSi samples that were chemically post-etched, the optical absorption decreased and the effective thermal diffusivity increased after UV irradiation. This indicates that NSi samples that are post-etched are more readily affected by UV irradiation, i.e., oxidized by replacing Si-Hx bonds by Si-Ox, than those that do not undergo post-etching.
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Keyword(in English) Porous silicon / Photoacoustic technique / Optical absorption / Thermal diffusivity / UV irradiation
Paper # US2005-9
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Committee US
Conference Date 2005/5/6(1days)
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Registration To Ultrasonics (US)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Charactarization of Nanocrystalline Silicon using Photoacoustic Method
Sub Title (in English)
Keyword(1) Porous silicon
Keyword(2) Photoacoustic technique
Keyword(3) Optical absorption
Keyword(4) Thermal diffusivity
Keyword(5) UV irradiation
1st Author's Name Masashi INOGUCHI
1st Author's Affiliation Dept. Appl. Phys. & Chem., Univ. Electro-Commun()
2nd Author's Name Qing Shen
2nd Author's Affiliation Dept. Appl. Phys. & Chem., Univ. Electro-Commun:Course of Coherent Optical Science, Univ. Electro-Commun
3rd Author's Name Taro TOYODA
3rd Author's Affiliation Dept. Appl. Phys. & Chem., Univ. Electro-Commun:Course of Coherent Optical Science, Univ. Electro-Commun
Date 2005/5/6
Paper # US2005-9
Volume (vol) vol.105
Number (no) 44
Page pp.pp.-
#Pages 6
Date of Issue