Presentation | 2000/4/28 Chiroptical Switch and Memory of Induced Circular Dichroism of Poly(alkyl-alkoxyphenylsilane)s in Solution and as Aggregates Hiroshi Nakashima, Michiya Fujiki, Masao Motonaga, Julian R. Koe, |
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Abstract(in Japanese) | (See Japanese page) |
Abstract(in English) | This paper reports the synthesis and chiroptical properties of poly(alkyl-alkoxyphenylsilane)s in dilute solutions and as aggregates. We observed marked substitutent effects on the UV/circular dichroism(CD) absorption characteristics and silicon main-chain conformational structures for the polysilanes in molecularly dispersed solution. In addition, the aggregates of the polysilanes showed switchable and memorisable induced CD properties dependent on some external stimulus (chemical or thermal). |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | polysilane / optical activity / molecularly dispersion / aggregates / circular dichroism switch / circular dichroism memory |
Paper # | OME2000-12 |
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Committee | OME |
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Conference Date | 2000/4/28(1days) |
Place (in Japanese) | (See Japanese page) |
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Registration To | Organic Material Electronics (OME) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | Chiroptical Switch and Memory of Induced Circular Dichroism of Poly(alkyl-alkoxyphenylsilane)s in Solution and as Aggregates |
Sub Title (in English) | |
Keyword(1) | polysilane |
Keyword(2) | optical activity |
Keyword(3) | molecularly dispersion |
Keyword(4) | aggregates |
Keyword(5) | circular dichroism switch |
Keyword(6) | circular dichroism memory |
1st Author's Name | Hiroshi Nakashima |
1st Author's Affiliation | NTT Basic Research Labs:CREST-JST() |
2nd Author's Name | Michiya Fujiki |
2nd Author's Affiliation | NTT Basic Research Labs:CREST-JST |
3rd Author's Name | Masao Motonaga |
3rd Author's Affiliation | NTT Basic Research Labs:CREST-JST |
4th Author's Name | Julian R. Koe |
4th Author's Affiliation | NTT Basic Research Labs:CREST-JST |
Date | 2000/4/28 |
Paper # | OME2000-12 |
Volume (vol) | vol.100 |
Number (no) | 29 |
Page | pp.pp.- |
#Pages | 6 |
Date of Issue |