| Presentation | 1999/2/6 Chiroptical Properties and Helix-coil Transition of Semiflexible Optically Active Organopolysilane Michiya Fujiki, |
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| PDF Download Page | PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | The present paper reports chiroptical properties of semiflexible, optically active organopolysilane (1__-) in isooctane solution. Polysilane (1__-) showed helix-coil transition at-11℃. The helix-coil transition reversely took place when solution was heated up and coiled down. Below the temperature, 1__- took a rodlike, single-screw-sense helical conformation, while above the temperature 1__- took random-coiled conformation with an almost equal amount or right-handed and left-handed helical segments. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | polysilane / helix / optical activity / chiral / cooperative phenomenon / exciton / Helix-coil Transition |
| Paper # | OME98-133 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 1999/2/6(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Chiroptical Properties and Helix-coil Transition of Semiflexible Optically Active Organopolysilane |
| Sub Title (in English) | |
| Keyword(1) | polysilane |
| Keyword(2) | helix |
| Keyword(3) | optical activity |
| Keyword(4) | chiral |
| Keyword(5) | cooperative phenomenon |
| Keyword(6) | exciton |
| Keyword(7) | Helix-coil Transition |
| 1st Author's Name | Michiya Fujiki |
| 1st Author's Affiliation | NTT Basic Research laboratories CREST() |
| Date | 1999/2/6 |
| Paper # | OME98-133 |
| Volume (vol) | vol.98 |
| Number (no) | 581 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |