| Presentation | 1998/5/6 Synthesis and Photoreaction of Network Polysilanes Prepared by a Disproportionation Reaction Keiji Kabeta, Shigeru Wakamatsu, Shinichiro Sugi, Takafumi Imai, |
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| PDF Download Page | PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Preparation of polysilanes was investigated by a catalytic disproportionation reaction of alkoxydisilanes. Oraganic substituents other than a methyl group were introduced into polysilanes by two methods: (1) disproportionation reaction in the presence of substituted alkoxysilanes, (2) disproportionation reaction initiated with a small amount of organolithium reagents. Alkylene and arylene groups as well as alkyl and aryl groups were successfully introduced into the polysilanes by these methods. The decrease in molecular weight of the polysilanes was considerably small during a photooxidation reaction, presumably due to their network structure and alkoxy substituents. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Polysilane / Network / Disproportionation / Alkoxypolysilane / Photoreaction / Photooxidation |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 1998/5/6(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Synthesis and Photoreaction of Network Polysilanes Prepared by a Disproportionation Reaction |
| Sub Title (in English) | |
| Keyword(1) | Polysilane |
| Keyword(2) | Network |
| Keyword(3) | Disproportionation |
| Keyword(4) | Alkoxypolysilane |
| Keyword(5) | Photoreaction |
| Keyword(6) | Photooxidation |
| 1st Author's Name | Keiji Kabeta |
| 1st Author's Affiliation | Technology Center, Toshiba Silicone Co., Ltd.() |
| 2nd Author's Name | Shigeru Wakamatsu |
| 2nd Author's Affiliation | Technology Center, Toshiba Silicone Co., Ltd. |
| 3rd Author's Name | Shinichiro Sugi |
| 3rd Author's Affiliation | Technology Center, Toshiba Silicone Co., Ltd. |
| 4th Author's Name | Takafumi Imai |
| 4th Author's Affiliation | Technology Center, Toshiba Silicone Co., Ltd. |
| Date | 1998/5/6 |
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| Volume (vol) | vol.98 |
| Number (no) | 38 |
| Page | pp.pp.- |
| #Pages | 6 |
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