Presentation | 1998/5/6 Preparation and Structure of a Polysilane Bearing Optically Active Substituents in the Side Chain D. Terunuma, K. Nagumo, Y. Amano, N. Kamata, K. Matsuoka, H. Kuzuhara, |
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Abstract(in Japanese) | (See Japanese page) |
Abstract(in English) | Polyhexylphenysilane was prepared by Wurtz reaction, and it was treated with chloromethylmethyl ether in the presence of tin tetrachloride to give a chloromethylated polysilane derivative. It was noted that the chloromethyl substituents were introduced in the p-position to silicon. The chloromethylated polysilane was treated with optically active N, N-dimethyl-α-methylbenzylamine to yield a polysilane bearing optically active substituents. Circular dichromic spectrum of the polymer in ethanol showed that the polysilane has screw-sense conformation. |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | synthesis / polysilane / chloromethylation / CD spectrum / screw-sense conformation |
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Conference Information | |
Committee | OME |
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Conference Date | 1998/5/6(1days) |
Place (in Japanese) | (See Japanese page) |
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Topics (in Japanese) | (See Japanese page) |
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Registration To | Organic Material Electronics (OME) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | Preparation and Structure of a Polysilane Bearing Optically Active Substituents in the Side Chain |
Sub Title (in English) | |
Keyword(1) | synthesis |
Keyword(2) | polysilane |
Keyword(3) | chloromethylation |
Keyword(4) | CD spectrum |
Keyword(5) | screw-sense conformation |
1st Author's Name | D. Terunuma |
1st Author's Affiliation | Department of Functional Materials Science, Saitama University() |
2nd Author's Name | K. Nagumo |
2nd Author's Affiliation | Department of Functional Materials Science, Saitama University |
3rd Author's Name | Y. Amano |
3rd Author's Affiliation | Department of Functional Materials Science, Saitama University |
4th Author's Name | N. Kamata |
4th Author's Affiliation | Department of Functional Materials Science, Saitama University |
5th Author's Name | K. Matsuoka |
5th Author's Affiliation | Department of Functional Materials Science, Saitama University |
6th Author's Name | H. Kuzuhara |
6th Author's Affiliation | Department of Functional Materials Science, Saitama University |
Date | 1998/5/6 |
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Volume (vol) | vol.98 |
Number (no) | 38 |
Page | pp.pp.- |
#Pages | 6 |
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