| Presentation | 1998/5/6 Preparation and Structure of a Polysilane Bearing Optically Active Substituents in the Side Chain D. Terunuma, K. Nagumo, Y. Amano, N. Kamata, K. Matsuoka, H. Kuzuhara, |
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| PDF Download Page | PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Polyhexylphenysilane was prepared by Wurtz reaction, and it was treated with chloromethylmethyl ether in the presence of tin tetrachloride to give a chloromethylated polysilane derivative. It was noted that the chloromethyl substituents were introduced in the p-position to silicon. The chloromethylated polysilane was treated with optically active N, N-dimethyl-α-methylbenzylamine to yield a polysilane bearing optically active substituents. Circular dichromic spectrum of the polymer in ethanol showed that the polysilane has screw-sense conformation. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | synthesis / polysilane / chloromethylation / CD spectrum / screw-sense conformation |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 1998/5/6(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Preparation and Structure of a Polysilane Bearing Optically Active Substituents in the Side Chain |
| Sub Title (in English) | |
| Keyword(1) | synthesis |
| Keyword(2) | polysilane |
| Keyword(3) | chloromethylation |
| Keyword(4) | CD spectrum |
| Keyword(5) | screw-sense conformation |
| 1st Author's Name | D. Terunuma |
| 1st Author's Affiliation | Department of Functional Materials Science, Saitama University() |
| 2nd Author's Name | K. Nagumo |
| 2nd Author's Affiliation | Department of Functional Materials Science, Saitama University |
| 3rd Author's Name | Y. Amano |
| 3rd Author's Affiliation | Department of Functional Materials Science, Saitama University |
| 4th Author's Name | N. Kamata |
| 4th Author's Affiliation | Department of Functional Materials Science, Saitama University |
| 5th Author's Name | K. Matsuoka |
| 5th Author's Affiliation | Department of Functional Materials Science, Saitama University |
| 6th Author's Name | H. Kuzuhara |
| 6th Author's Affiliation | Department of Functional Materials Science, Saitama University |
| Date | 1998/5/6 |
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| Volume (vol) | vol.98 |
| Number (no) | 38 |
| Page | pp.pp.- |
| #Pages | 6 |
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