| Presentation | 1997/11/21 Synthsis of C60 Compound Polymer from Solution H. Endo, Y. Nagayama, T. Watanabe, H. Yamamoto, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | We tried to synthesize a new class of MC60 compounds with M=Rb, Sr and Y by an electrolysis process from solution. Two kinds of solution, 1.5mmol/l-C60 Toluene and 0.1mol/l-M (ClO4)x (x=1, M=Rb; x=2, M=Sr; x=3, M=Y) N, N-Dimethylformamide, was filled in the cathode cell and the anode cell, respectively. An ion exchange membrane separated the solution. Electrochemical properties were measured for the electrolyte solution. A black film was deposited on a silver cathode plate after the electrolysis. A Raman spectrum revealed that C60 molecules existed and were polymerized in the film. Characteristic shape of particles were observed in the obtained film. The coexistence of both C60 and metal was confirmed in the particles by an energy dispersive x-ray spectrometer. The film was crystallized after a post annealing at 160℃ in a vacuum. The slowly cooled film after the annealing had a polymeric body-centered orthorhombic M1C60 phase, while the rapidly cooled film revealed a face centered cubic phase. Especially the polymeric Sr1C60 and Y1C60 were newly obtained and studied in this work, though the polymeric Rb1C60 has been well known. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | C60 / electrolysis / Rb1C60 / Sr1C60 / Y1C60 / polymeric phase |
| Paper # | OME97-99 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 1997/11/21(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Synthsis of C60 Compound Polymer from Solution |
| Sub Title (in English) | |
| Keyword(1) | C60 |
| Keyword(2) | electrolysis |
| Keyword(3) | Rb1C60 |
| Keyword(4) | Sr1C60 |
| Keyword(5) | Y1C60 |
| Keyword(6) | polymeric phase |
| 1st Author's Name | H. Endo |
| 1st Author's Affiliation | College of Sci. & Tecnhol., Nihon University() |
| 2nd Author's Name | Y. Nagayama |
| 2nd Author's Affiliation | College of Sci. & Tecnhol., Nihon University |
| 3rd Author's Name | T. Watanabe |
| 3rd Author's Affiliation | College of Sci. & Tecnhol., Nihon University |
| 4th Author's Name | H. Yamamoto |
| 4th Author's Affiliation | College of Sci. & Tecnhol., Nihon University |
| Date | 1997/11/21 |
| Paper # | OME97-99 |
| Volume (vol) | vol.97 |
| Number (no) | 394 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |