Presentation 1997/6/9
PHOTO-INDUCED ELECTRON TRANSFER IN DNA MONOLAYER : Fluoresence Quenching and Photocurrent Generation in DNA Monolayer
Toshiaki Ikeda, Fumio Nakamura, Kuniharu Ijiro, Masatsugu Shimomura,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Owing to one-dimensionallyarrayed π-electrons, so-called "π-ways", of stacked nucleobasesalong the polymer chain, double-stranded DNA can act as a molecular wire. DNA can form polyion complexes with cationic monolayers at the air-water interface. Fluorescencequenching of octadecylacridineorange (C18AO) by an amphphilic viologene in a dialkylammonium monolayer was enhanced by complexation with DNA. The cationic monolayer containing C18AO was transferred on an ITO electrode from an aqueous polymer subphase. Photocurrentwas generated when the modified electrode of DNA or RNA monolayer was irradiated with visible light (>450nm) in aqueous solution containing EDTA as a sacrificial electron doner.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) DNA / Monolayer / Photoinduced Electron Transfer / Intercalation / the Air-Water Interface / Photocurrent
Paper # OME97-28
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Conference Information
Committee OME
Conference Date 1997/6/9(1days)
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Registration To Organic Material Electronics (OME)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) PHOTO-INDUCED ELECTRON TRANSFER IN DNA MONOLAYER : Fluoresence Quenching and Photocurrent Generation in DNA Monolayer
Sub Title (in English)
Keyword(1) DNA
Keyword(2) Monolayer
Keyword(3) Photoinduced Electron Transfer
Keyword(4) Intercalation
Keyword(5) the Air-Water Interface
Keyword(6) Photocurrent
1st Author's Name Toshiaki Ikeda
1st Author's Affiliation Research Institute for Electronic Science, Hokkaido University()
2nd Author's Name Fumio Nakamura
2nd Author's Affiliation Research Institute for Electronic Science, Hokkaido University
3rd Author's Name Kuniharu Ijiro
3rd Author's Affiliation PRESTO, JST
4th Author's Name Masatsugu Shimomura
4th Author's Affiliation Research Institute for Electronic Science, Hokkaido University
Date 1997/6/9
Paper # OME97-28
Volume (vol) vol.97
Number (no) 88
Page pp.pp.-
#Pages 6
Date of Issue