Presentation | 1995/7/7 Synthesis of A1C60 film by electrolysis H. Endo, K. Yamaguchi, N. Yoshiyama, H. Yamamoto, |
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Abstract(in Japanese) | (See Japanese page) |
Abstract(in English) | Recently a polymeric A1C60 phase (A:alkali metals) has been mentioned as a new class of functional Fullerene compounds. In this work we firstly succeeded in a synthesis of the polymeric Rb1C60 phase by an electrolysis technique. The used electrolyte solution was the mixture of 0.3 mM-C60, 0.1 N-RbClO4 and N, N-Dimethylformamide (DMF)/Toluene (1:1). The anode and the cathode were silver plates and the reference electrode was Ag/Ag^+. The typical conditions of the electrolysis were as the following : the current density of 0.5μA/cm^2, the deposition time of 10~200hr, and the reaction temperature of 10~60℃. After the electrolysis a black film was obtained on the cathode plate. It was found from the observation of the film microstructure that the film growth mode was strongly dependent on the reaction temperature. The spindle-like structure with the length of about 1μ m was observed in the film deposited under comparatively high temperature. The existence of the polymeric Rb1C60 phase was also Confirmed in the film. |
Keyword(in Japanese) | (See Japanese page) |
Keyword(in English) | Fullerene / A1C60 / Polymer / Electrochemical polymerization / Microstructure |
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Conference Information | |
Committee | CPM |
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Conference Date | 1995/7/7(1days) |
Place (in Japanese) | (See Japanese page) |
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Paper Information | |
Registration To | Component Parts and Materials (CPM) |
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Language | JPN |
Title (in Japanese) | (See Japanese page) |
Sub Title (in Japanese) | (See Japanese page) |
Title (in English) | Synthesis of A1C60 film by electrolysis |
Sub Title (in English) | |
Keyword(1) | Fullerene |
Keyword(2) | A1C60 |
Keyword(3) | Polymer |
Keyword(4) | Electrochemical polymerization |
Keyword(5) | Microstructure |
1st Author's Name | H. Endo |
1st Author's Affiliation | College of Sci. & Technol., Nihon Univ.() |
2nd Author's Name | K. Yamaguchi |
2nd Author's Affiliation | College of Sci. & Technol., Nihon Univ. |
3rd Author's Name | N. Yoshiyama |
3rd Author's Affiliation | College of Sci. & Technol., Nihon Univ. |
4th Author's Name | H. Yamamoto |
4th Author's Affiliation | College of Sci. & Technol., Nihon Univ. |
Date | 1995/7/7 |
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Volume (vol) | vol.95 |
Number (no) | 138 |
Page | pp.pp.- |
#Pages | 5 |
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