Presentation 2002/6/14
Thermal Chemical Vapor Deposition of Zirconium/Hafnium-Silicate Thin-Film Using TEOS and tert-butoxide
Seiji INUMIYA, Dawei GAO, Kazuhiro EGUCHI,
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Abstract(in English) Zirconium/Hafnium-silicates are the attractive materials for the alternative gate dielectrics, which are applicable to conventional CMOS integrations with polycrystalline silicon gate electrodes. We found the deposition rate enhancement in the thermal chemical vapor deposition by using TEOS and zirconium/hafnium tert-butoxide. The deposited films have desirable ZrO_2/HfO_2 contents of 10 to 30% for the gate dielectrics and they are controllable by mean of the source gas mixture ratio. The concentration of residual carbon is under the detection level of the XPS analysis. The bonding state of the deposited film suggests the high resistance to phase separation and crystallization.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) High-k / gate dielectric / Zr-silicate / Hf-silicate / thermal chemical vapor deposition / TEOS / tert-butoxide
Paper # SDM2002-59
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Committee SDM
Conference Date 2002/6/14(1days)
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Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Thermal Chemical Vapor Deposition of Zirconium/Hafnium-Silicate Thin-Film Using TEOS and tert-butoxide
Sub Title (in English)
Keyword(1) High-k
Keyword(2) gate dielectric
Keyword(3) Zr-silicate
Keyword(4) Hf-silicate
Keyword(5) thermal chemical vapor deposition
Keyword(6) TEOS
Keyword(7) tert-butoxide
1st Author's Name Seiji INUMIYA
1st Author's Affiliation Process & Manufacturing Engineering Center, Semiconductor Company, TOSHIBA Corporation()
2nd Author's Name Dawei GAO
2nd Author's Affiliation Process & Manufacturing Engineering Center, Semiconductor Company, TOSHIBA Corporation
3rd Author's Name Kazuhiro EGUCHI
3rd Author's Affiliation Process & Manufacturing Engineering Center, Semiconductor Company, TOSHIBA Corporation
Date 2002/6/14
Paper # SDM2002-59
Volume (vol) vol.102
Number (no) 134
Page pp.pp.-
#Pages 6
Date of Issue