Presentation 2001/3/6
Degradation of Pt/PLZT/Pt Capacitors Caused by Hydroxyl Group in Interlayer Dielectrics
Kazufumi Suenaga, Kiyoshi Ogata, Hiromichi Waki, Mitsuhiro Mori,
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Abstract(in English) A correlation between ferroelectric properties of the Pt/PLZT/Pt capacitors and amount of H_2 and H_2O gasses desorbed from interlayer dielectrics were investigated quantitatively. H_2 and H_2O gasses were analyzed using thermal desorption spectroscopy. Polarization charges and its aging characteristics of memory array capacitors with area of 2μm squares did not depend on amount of desorbed H_2 explicitly, but strongly on H_2O desorption. It is considered that hydrogen atoms were mainly dissociated from H_2O molecules by catalytic activities of Pt top electrodes. Precise control of hydroxyl groups contained in interlayer dielectrics and passivation films resulted in very small retention degradation caused by imprint phenomena, and realized high reliability and high density FRAM technologies.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) ferroelectric / PLZT / imprint / dielectrics / hydroxyl group / TDS
Paper # SDM2000-239
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Conference Information
Committee SDM
Conference Date 2001/3/6(1days)
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Paper Information
Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Degradation of Pt/PLZT/Pt Capacitors Caused by Hydroxyl Group in Interlayer Dielectrics
Sub Title (in English)
Keyword(1) ferroelectric
Keyword(2) PLZT
Keyword(3) imprint
Keyword(4) dielectrics
Keyword(5) hydroxyl group
Keyword(6) TDS
1st Author's Name Kazufumi Suenaga
1st Author's Affiliation Production Engineering Research Laboratory, Hitachi, Ltd.()
2nd Author's Name Kiyoshi Ogata
2nd Author's Affiliation Production Engineering Research Laboratory, Hitachi, Ltd.
3rd Author's Name Hiromichi Waki
3rd Author's Affiliation Semiconductor and Integrated Circuits, Hitachi, Ltd.
4th Author's Name Mitsuhiro Mori
4th Author's Affiliation Semiconductor and Integrated Circuits, Hitachi, Ltd.
Date 2001/3/6
Paper # SDM2000-239
Volume (vol) vol.100
Number (no) 653
Page pp.pp.-
#Pages 5
Date of Issue