Presentation 1999/2/15
Analysis of Decomposed Layer Appearing on the Surface of Barium Strontium Titanate
Yoshihisa Fujisaki, Yasuhiro Shimamoto, Kazuyoshi Torii, Yuichi Matsui,
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Abstract(in English) Chemical states and structures of thin degenerated layers grown on the surface of (Ba,Sr)TiO_3(BST) films are investigated by X-ray photoelectron spectroscopy (XPS). It was found that decomposition occurred as a result of the air exposure and also as a result of annealing. A careful study of a Ba 3d peak in the XPS spectrum reveals that Ba in BST crystal easily decomposes out of the perovskite phase and makes BaCO_3 or barium oxides, whereas no significant change occurs in Sr, or Ti oxides. This degenerated layer can be removed by nitric acid treatment. It was also found that the surface BST becomes rather stable against exposure to air compared with the original one after the nitric acid treatment.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) BST / XPS / decomposition / nitric acid / surface treatment / humidity
Paper # ED98-244
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Committee SDM
Conference Date 1999/2/15(1days)
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Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Analysis of Decomposed Layer Appearing on the Surface of Barium Strontium Titanate
Sub Title (in English)
Keyword(1) BST
Keyword(2) XPS
Keyword(3) decomposition
Keyword(4) nitric acid
Keyword(5) surface treatment
Keyword(6) humidity
1st Author's Name Yoshihisa Fujisaki
1st Author's Affiliation Central Research Laboratory, Hitachi Ltd.()
2nd Author's Name Yasuhiro Shimamoto
2nd Author's Affiliation Central Research Laboratory, Hitachi Ltd.
3rd Author's Name Kazuyoshi Torii
3rd Author's Affiliation Central Research Laboratory, Hitachi Ltd.
4th Author's Name Yuichi Matsui
4th Author's Affiliation Central Research Laboratory, Hitachi Ltd.
Date 1999/2/15
Paper # ED98-244
Volume (vol) vol.98
Number (no) 592
Page pp.pp.-
#Pages 7
Date of Issue