Presentation 1998/8/20
Atomic-Layer Thermal Nitridation Process of Si (100) Using NH_3
Takeshi WATANABE, Masao SAKURABA, Takashi MATSUURA, Junichi MUROTA,
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Abstract(in English) Atomic-layer nitridation jof Si (100) in NH_3 has been investigated using an ultraclean low pressure cold-wall reactor system with flash heating in order to separate surface adsorption and reaction of HN_3. The N atom concentration (n_N) on Si (100) nitridized at 400℃ in NH_3 with flash heating by light irradiation of 60 J/cm^2 per shot initially increases with nitridation time (Xe flash light irradiation number) and tends to saturate to a certain value (~2.7×10^<15>cm^-2). The reaction efficiency of NH_3 drastically increases as compared to the thermal nitridation without flash heating. By separating adsorption and reaction of NH_3, it is expected that NH_3 physically adsorbs on Si (100) according to Langmuir-type adsorption and then reaction proceeds. It was found by XPS that flash heated nitridation proceeds in the backbond of the surface Si atoms as well as thermal nitridation at 650℃.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) atomic-layer / nitridation / Si / NH_3 / flash heating / Langmuir-type
Paper # SDM98-121
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Conference Information
Committee SDM
Conference Date 1998/8/20(1days)
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Paper Information
Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Atomic-Layer Thermal Nitridation Process of Si (100) Using NH_3
Sub Title (in English)
Keyword(1) atomic-layer
Keyword(2) nitridation
Keyword(3) Si
Keyword(4) NH_3
Keyword(5) flash heating
Keyword(6) Langmuir-type
1st Author's Name Takeshi WATANABE
1st Author's Affiliation Laboratory for Electronic Intelligent Systems, Research Institute of Electrical Communication, Tohoku University()
2nd Author's Name Masao SAKURABA
2nd Author's Affiliation Laboratory for Electronic Intelligent Systems, Research Institute of Electrical Communication, Tohoku University
3rd Author's Name Takashi MATSUURA
3rd Author's Affiliation Laboratory for Electronic Intelligent Systems, Research Institute of Electrical Communication, Tohoku University
4th Author's Name Junichi MUROTA
4th Author's Affiliation Laboratory for Electronic Intelligent Systems, Research Institute of Electrical Communication, Tohoku University
Date 1998/8/20
Paper # SDM98-121
Volume (vol) vol.98
Number (no) 242
Page pp.pp.-
#Pages 6
Date of Issue