Presentation 1996/12/5
Structural relaxation in gate oxide by phosphorous redistribution
K. Morino, S. Miyazaki, M. Hirose,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Phosphorus incorporation and the structural modification in ultra-thin gate oxides for fabricating n^+ Poly-Si gates have been systematically investigated by using XPS and FT-IR-ATR. It is found that diffused phosphorus atoms in gate oxides pile up near the SiO_2/c-Si interface when phosphorus diffusion is carried out at 900℃ for 10 min for undoped poly-Si gate and subsequent annealing at 900℃ for 10 min. P2p XB core level spectra indicate four-fold coordinated phosphorus atoms in the oxide together with a three-fold coordinated P=0 double bonds in the Si0_2 network. Also a red shift in the SiO_2 LO phonon frequency observed in a region within 2nm from the interface is small in the case of phosphorus doped SiO_2 as compared to the case of pure SiO_2. This implies that compressive stress near the Si0_2/c-Si interface is relaxed by incorporation of three-fold coordinated phosphorus atoms in the Si0_2 matrix It is also verified that no significant change in the valence band density of states and the bandgap value of SiO_2 is caused by phosphorus incorporation up to 4x10^<20>cm^<-3>
Keyword(in Japanese) (See Japanese page)
Keyword(in English) phosphorus / redistribution / pile-up / compressive stress / structural relaxation
Paper # SDM96-147
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Conference Information
Committee SDM
Conference Date 1996/12/5(1days)
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Paper Information
Registration To Silicon Device and Materials (SDM)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Structural relaxation in gate oxide by phosphorous redistribution
Sub Title (in English)
Keyword(1) phosphorus
Keyword(2) redistribution
Keyword(3) pile-up
Keyword(4) compressive stress
Keyword(5) structural relaxation
1st Author's Name K. Morino
1st Author's Affiliation Department of Electrical Engineering, Hiroshima University()
2nd Author's Name S. Miyazaki
2nd Author's Affiliation Department of Electrical Engineering, Hiroshima University
3rd Author's Name M. Hirose
3rd Author's Affiliation Department of Electrical Engineering, Hiroshima University
Date 1996/12/5
Paper # SDM96-147
Volume (vol) vol.96
Number (no) 395
Page pp.pp.-
#Pages 7
Date of Issue