Presentation 1996/11/21
Thermoanalytical study of phase-change optical recording medium
Chung Ping LIU, Der Ray HUANG, E Van LIAO, Yung Yuan CHANH, Don Yau CHIANG,
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Abstract(in English) In general, GeTeSb ternary alloy has been used as phase-change optical recording mrdium by using its differential reflectivity of crystalline phase or amorphous phase. In this experiment, GeTeSb film was deposited by using RF sputtering process. Thermal properties of GeTeSb film was measured with a differential sacnning calorimeter (DSC) under different heating rates. From DSC curves, the melting point of GeTeSb film is about 390℃ under different heating rates, while the crystallization temperature is varied under different heating rates. With heating rate increased from 10℃/min to 200℃/min, the crystakkization temperature is increased from 170℃ to 198℃. In real recording process of phase-change optical disk, the heating rate is much higher than 200℃/min. The three activation energy of crystalline phase respectively 1.86 eV, 1.93 eV, and 1.79 eV, can be obtained with Kissinger method. We can estimate the crystallization temperature in the recording process is around 230℃~250℃ by numerical extrapolation method from DSC data. It is a useful method to predict the thermal properties of phase change recording medium. A detailed experimental data and analysis will be discussed.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) phase change / DSC / crystallization temperature / activation energy thermal analysis
Paper # MR96-50
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Committee MR
Conference Date 1996/11/21(1days)
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Language ENG
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Thermoanalytical study of phase-change optical recording medium
Sub Title (in English)
Keyword(1) phase change
Keyword(2) DSC
Keyword(3) crystallization temperature
Keyword(4) activation energy thermal analysis
1st Author's Name Chung Ping LIU
1st Author's Affiliation Dept. of Electrical Engineering, Yuang-Ze Institute of Technology, Taoyuan()
2nd Author's Name Der Ray HUANG
2nd Author's Affiliation Opto-Electronics & Systems Lab., ITRI, Hsinchu
3rd Author's Name E Van LIAO
3rd Author's Affiliation Dept. of Physics, Fu-Jen Catholic University, Taipei
4th Author's Name Yung Yuan CHANH
4th Author's Affiliation Dept. of Physics, Fu-Jen Catholic University, Taipei
5th Author's Name Don Yau CHIANG
5th Author's Affiliation Opto-Electronics & Systems Lab., ITRI, Hsinchu
Date 1996/11/21
Paper # MR96-50
Volume (vol) vol.96
Number (no) 377
Page pp.pp.-
#Pages 7
Date of Issue