Presentation 1999/1/21
EPR investigations of europium(II)-doped aluminates with blue and green emission
K. Kaiya, N. Takahashi, T. Matsuzawa, T. Nakamura,
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Abstract(in English) EPR spectroscopy has been applied to investigate the europium(II)sites in europium(II)-doped aluminate phosphors with tridymite structure. X-band spectra of the phosphors are quite complicated to analyse due to large zero-field splittings, so that little information about europium(II)ions can be obtained. On the contrary, high-frequency EPR measured at 90 or 180 GHz shows symmetric spectra centred around about g=2.0. The spectral simulation confirmed that there is one site in the CaAl_2O_4, three in the SrAl_2O_4 and two in the BaAl_2O_4 in contrast to our expectations from crystallographic sites.
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Keyword(in English) EPR / europium(II) / long phosphorescence / aluminate / spectral simulation
Paper # EID98-84
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Conference Date 1999/1/21(1days)
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Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) EPR investigations of europium(II)-doped aluminates with blue and green emission
Sub Title (in English)
Keyword(1) EPR
Keyword(2) europium(II)
Keyword(3) long phosphorescence
Keyword(4) aluminate
Keyword(5) spectral simulation
1st Author's Name K. Kaiya
1st Author's Affiliation Faculty of Engineering, Shizuoka Univ.()
2nd Author's Name N. Takahashi
2nd Author's Affiliation Faculty of Engineering, Shizuoka Univ.
3rd Author's Name T. Matsuzawa
3rd Author's Affiliation R&D Center, Nemoto & Co.Ltd.
4th Author's Name T. Nakamura
4th Author's Affiliation Faculty of Engineering, Shizuoka Univ.
Date 1999/1/21
Paper # EID98-84
Volume (vol) vol.98
Number (no) 549
Page pp.pp.-
#Pages 5
Date of Issue