Presentation 1994/11/11
Nonlinear optical properties of the poly(aryleneethynylene)type π- conjugated polymers
Naoki Ohba, Satoru Tomaru, Wataru Yamada, Takakazu Yamamoto,
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Abstract(in English) Poly(aryleneethynylene)type π-conjugated polymers(PAEs)are synth esized and the third-order optical susceptibility X^(3)>of their thin films is evaluated.There is a red-shift in the electronic absorption of the PAE caused by an intramolecular charge transfer(CT)interaction when π-electron excessive heteroaromatic r ings are introduced.The X^(3)>value of the PAEs is enhanced by increasing the CT interaction and reaches more than 10^-11> esu in the near resonant region.The main factor enhancing X^(3)>is the increase in the π-electron delocalization caused by the CT int eraction.
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Keyword(in English) nonlinear optics / π-conjugated polymer / poly(aryleneethynylene ) / intramolecular charge charge transfer
Paper # EID94-80,OME94-62
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Committee EID
Conference Date 1994/11/11(1days)
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Language JPN
Title (in Japanese) (See Japanese page)
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Title (in English) Nonlinear optical properties of the poly(aryleneethynylene)type π- conjugated polymers
Sub Title (in English)
Keyword(1) nonlinear optics
Keyword(2) π-conjugated polymer
Keyword(3) poly(aryleneethynylene )
Keyword(4) intramolecular charge charge transfer
1st Author's Name Naoki Ohba
1st Author's Affiliation NTT Opto-electronics Laboratories()
2nd Author's Name Satoru Tomaru
2nd Author's Affiliation NTT Opto-electronics Laboratories
3rd Author's Name Wataru Yamada
3rd Author's Affiliation Research Laboratory of Resources Utilization,Tokyo Institute of Technology
4th Author's Name Takakazu Yamamoto
4th Author's Affiliation Research Laboratory of Resources Utilization,Tokyo Institute of Technology
Date 1994/11/11
Paper # EID94-80,OME94-62
Volume (vol) vol.94
Number (no) 327
Page pp.pp.-
#Pages 5
Date of Issue