| Presentation | 2004/9/2 Molecular Structure and Packing of Organopolysilanes with Asymmetric Side-Chains Masashi FURUKAWA, Hidetaka OHTA, |
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| PDF Download Page | PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | We have studied molecular structure and packing of various silicon-based polymers with symmetric side-chains. As a result, it is found that the two side-chains bonded to a silicon atom stretch asymmetrically due to the intra-molecular steric hindrance. These side-chains are bonded to the adjacent side-chains bonded to the second nearest- eighbor silicon atoms by van der Waals force. In this paper, molecular structure and packing of organopolysilanes with asymmetric side-chains, i.e., poly(methyl ethyl silane) and poly(methyl n-propyl silane), are examined by X-ray diffraction method. Difference and similarity between organopolysilanes with symmetric and asymmetric side-chains are discussed on the bases of the obtained structures. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Organopolysilane / Molecular Structure / Packing / van der Waals Force / Poly(methyl ethyl silane) / Poly(methyl n-propyl silane) |
| Paper # | ED2004-108,OME2004-42 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 2004/9/2(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Molecular Structure and Packing of Organopolysilanes with Asymmetric Side-Chains |
| Sub Title (in English) | |
| Keyword(1) | Organopolysilane |
| Keyword(2) | Molecular Structure |
| Keyword(3) | Packing |
| Keyword(4) | van der Waals Force |
| Keyword(5) | Poly(methyl ethyl silane) |
| Keyword(6) | Poly(methyl n-propyl silane) |
| 1st Author's Name | Masashi FURUKAWA |
| 1st Author's Affiliation | Graduate School of Computer Science and Systems Engineering, Kyushu Institute of Technology() |
| 2nd Author's Name | Hidetaka OHTA |
| 2nd Author's Affiliation | Graduate School of Computer Science and Systems Engineering, Kyushu Institute of Technology |
| Date | 2004/9/2 |
| Paper # | ED2004-108,OME2004-42 |
| Volume (vol) | vol.104 |
| Number (no) | 285 |
| Page | pp.pp.- |
| #Pages | 6 |
| Date of Issue | |