| Presentation | 2003/5/19 Second harmonic generation from unsymmetrical phthalocyanines Tsuyoshi MUTO, Tetsuya AOYAMA, Tatsuo WADA, Mutsumi KIMURA, Hirofusa SHIRAI, |
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| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | We have prepared a chiral unsymmetrical vanadyl phthalocyanine having one nitro and six (S)-2-methylbutoxy groups. A racemic analogue of this complex was also prepared by similar procedure. Both of the complexes were well soluble in organic solvents, and this allows us preparation of thin films using a spin-coating method. Spin-coated films prepared from a chloroform solution containing each of complexes and PMMA matrix exhibit the second harmonic activities after electric poling. Interestingly, the chiral complex showed larger second harmonic activity in refers to the racemic isomer. This difference is plausibly assigned to the molecular arrangements of each complexes in the polymer matrix. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Vanadylphthalocyanine / Unsymmetrical phthalocyanine / Second harmonic generation / Thin films |
| Paper # | OME2003-16 |
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| Conference Information | |
| Committee | OME |
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| Conference Date | 2003/5/19(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | |
| Topics (in Japanese) | (See Japanese page) |
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| Vice Chair | |
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| Paper Information | |
| Registration To | Organic Material Electronics (OME) |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Second harmonic generation from unsymmetrical phthalocyanines |
| Sub Title (in English) | |
| Keyword(1) | Vanadylphthalocyanine |
| Keyword(2) | Unsymmetrical phthalocyanine |
| Keyword(3) | Second harmonic generation |
| Keyword(4) | Thin films |
| 1st Author's Name | Tsuyoshi MUTO |
| 1st Author's Affiliation | Supramolecular Science Laboratory, RIKEN (The Institute of Physical & Chemical Research):Department of Functional Polymer Science & Technology, Faculty of Textile Science & Technology, Shinshu University() |
| 2nd Author's Name | Tetsuya AOYAMA |
| 2nd Author's Affiliation | Supramolecular Science Laboratory, RIKEN (The Institute of Physical & Chemical Research) |
| 3rd Author's Name | Tatsuo WADA |
| 3rd Author's Affiliation | Supramolecular Science Laboratory, RIKEN (The Institute of Physical & Chemical Research) |
| 4th Author's Name | Mutsumi KIMURA |
| 4th Author's Affiliation | Department of Functional Polymer Science & Technology, Faculty of Textile Science & Technology, Shinshu University |
| 5th Author's Name | Hirofusa SHIRAI |
| 5th Author's Affiliation | Department of Functional Polymer Science & Technology, Faculty of Textile Science & Technology, Shinshu University |
| Date | 2003/5/19 |
| Paper # | OME2003-16 |
| Volume (vol) | vol.103 |
| Number (no) | 84 |
| Page | pp.pp.- |
| #Pages | 4 |
| Date of Issue | |