Presentation 2003/1/18
Development of the Electrochemical Quantitative and Qualitative Analysis for Adsorbates on Pt Electrodes
Kosuke HAYAMA, Hiroki TANAKA, Kenshi HAYASHI, Kiyoshi TOKO,
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Abstract(in English) Quick and easy surface-analysis technology has been developed using two electrochemical methods, aiming multi-purpose chemical sensor developments; the surface-polarity controlling method and cyclic voltammetry. Aromatic compounds, amine and alcohol were measured using the surface-polarity controlling method. As a result of principal component analysis, responds of these compounds located in the region different each other for benzene rings, amino groups and hydroxyl groups respectively. Changes of impedance after cleaning has been suggested that adsorption of aromatic compounds on Pt surface is irreversible. The adsorption was confirmed using cyclic voltammetry in 0.5 M H_2SO_4. Continuous cyclic voltammograms indicated that a gradual decrease of adsorbate coverate was observed, and the clean Pt surface could be recovered.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Surface-polarity controlling method / Cyclic voltammetry / Pt / Aromatic compounds / Adsorption
Paper # MBE2002-110
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Conference Information
Committee MBE
Conference Date 2003/1/18(1days)
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Paper Information
Registration To ME and Bio Cybernetics (MBE)
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Development of the Electrochemical Quantitative and Qualitative Analysis for Adsorbates on Pt Electrodes
Sub Title (in English)
Keyword(1) Surface-polarity controlling method
Keyword(2) Cyclic voltammetry
Keyword(3) Pt
Keyword(4) Aromatic compounds
Keyword(5) Adsorption
1st Author's Name Kosuke HAYAMA
1st Author's Affiliation Graduate School of Information Science and Electrical Engineering, Kyushu University()
2nd Author's Name Hiroki TANAKA
2nd Author's Affiliation Graduate School of Information Science and Electrical Engineering, Kyushu University
3rd Author's Name Kenshi HAYASHI
3rd Author's Affiliation Graduate School of Information Science and Electrical Engineering, Kyushu University
4th Author's Name Kiyoshi TOKO
4th Author's Affiliation Graduate School of Information Science and Electrical Engineering, Kyushu University
Date 2003/1/18
Paper # MBE2002-110
Volume (vol) vol.102
Number (no) 597
Page pp.pp.-
#Pages 4
Date of Issue