Presentation 2017-01-27
Charge transfer state of Eu3+ centers activated in (La, Gd)-O-F-S and Y-Si-O-N
Masahiro Okada, Tadashi Ishigaki, Ryo Yoshimatsu, Tetsuo Honma, Koutoku Ohmi,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Novel red emitting phosphors having a blue excitation and a red emission due to charge transfer state (CTS) of Eu3+ centers have been synthesized. The wavelength region of the CTS excitation band strongly depends on the iconicity / covalency degree of the host materials. In this study, we have systematically investigated the Eu3+ CTS energy in the (La, Gd)-O-F-S and Y-Si-O-N based phosphors. It has been found the strong correlation between the coordination environment around Eu3+ centers and the absorption wavelength range of the CTS. In addition, it has been also found that the band gap energy of the host materials correlates well with the CTS energy.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) charge transfer state (CTS) / La-O-F-S:Eu3+ / Y-Si-O-N:Eu3+
Paper # EID2016-44
Date of Issue 2017-01-19 (EID)

Conference Information
Committee EID / ITE-IDY / IEE-EDD / IEIJ-SSL / SID-JC
Conference Date 2017/1/26(2days)
Place (in Japanese) (See Japanese page)
Place (in English) Tokushima Univ.
Topics (in Japanese) (See Japanese page)
Topics (in English) Joint Meeting of Emissive/Non-emissive Displays
Chair Tomokazu Shiga(Univ. of Electro-Comm.) / Keiichi Betsui(Hitachi)
Vice Chair Mutsumi Kimura(Ryukoku Univ.) / Yuko Kominami(Shizuoka Univ.) / Yoshihide Fujisaki(NHK)
Secretary Mutsumi Kimura(NTT) / Yuko Kominami(Tokyo Inst. of Tech.) / Yoshihide Fujisaki(Shizuoka Univ.)
Assistant Rumiko Yamaguchi(Akita Univ.) / Hiroyuki Nitta(Japan Display) / Mitsuru Nakata(NHK) / Takashi Kojiri(ZEON) / Ryosuke Nonaka(Toshiba)

Paper Information
Registration To Technical Committee on Electronic Information Displays / Technical Group on Information Display / Technical Group on Electron Devices / * / Society for Information Display Japan Chapter
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Charge transfer state of Eu3+ centers activated in (La, Gd)-O-F-S and Y-Si-O-N
Sub Title (in English)
Keyword(1) charge transfer state (CTS)
Keyword(2) La-O-F-S:Eu3+
Keyword(3) Y-Si-O-N:Eu3+
1st Author's Name Masahiro Okada
1st Author's Affiliation Tottori University(Tottori Univ.)
2nd Author's Name Tadashi Ishigaki
2nd Author's Affiliation Tottori University(Tottori Univ.)
3rd Author's Name Ryo Yoshimatsu
3rd Author's Affiliation Denka Company Limited(Denka)
4th Author's Name Tetsuo Honma
4th Author's Affiliation Japan Synchrotron Radiation Research Institute(JASRI)
5th Author's Name Koutoku Ohmi
5th Author's Affiliation Tottori University(Tottori Univ.)
Date 2017-01-27
Paper # EID2016-44
Volume (vol) vol.116
Number (no) EID-430
Page pp.pp.121-124(EID),
#Pages 4
Date of Issue 2017-01-19 (EID)