Presentation 2023-12-08
Protection Methods of Graphene-Oxide-Semiconductor Electron Emission Sources against Oxidizing Environments and Their Effects on Electron Emission Properties
Ren Mutsukawa, Yoshinori Takao, Masayoshi Nagao, Hiromasa Murata, Katsuhisa Murakami,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Graphene-oxide-semiconductor (GOS) electron emission devices can emit electrons at low voltages, which are expected to be used as a neutralizer for ion thrusters. However, the GOS devices are vulnerable to atomic oxygen (AO). To improve their oxidation resistance, hexagonal boron nitride (h-BN) was deposited by thermal chemical vapor deposition (CVD), and aluminum oxide was deposited by atomic layer deposition (ALD) as a protective layer. After the exposure to the O2 radical generated by oxygen plasma, we measured the Raman spectra of the graphene electrodes and optical transmittance of the protective films. The results showed that a 4.06 nm aluminum oxide protective layer deposited by ALD protected the graphene even after 30 minutes of oxygen plasma exposure, corresponding to about 100 hours of operation in low earth orbit. We also measured electron emission characteristics and found that the GOS electron emission device with an alumina protective layer was able to emit electrons.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Graphene-Oxide-Semiconductor / Graphene / Hexagonal Boron Nitride / Aluminum Oxide / Low Earth Orbit
Paper # ED2023-48
Date of Issue 2023-11-30 (ED)

Conference Information
Committee ED
Conference Date 2023/12/7(2days)
Place (in Japanese) (See Japanese page)
Place (in English) WINC AICHI
Topics (in Japanese) (See Japanese page)
Topics (in English) Applications of electron and ion beam
Chair Seiya Sakai(Hokkaido Univ.)
Vice Chair Manabu Arai(Nagoya Univ.)
Secretary Manabu Arai(Saga Univ.)
Assistant Masatoshi Koyama(Osaka Inst. of Tech.) / Tomohiro Yoshida(SUMITOMO ELECTRIC DEVICE INNOVATIONS)

Paper Information
Registration To Technical Committee on Electron Devices
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Protection Methods of Graphene-Oxide-Semiconductor Electron Emission Sources against Oxidizing Environments and Their Effects on Electron Emission Properties
Sub Title (in English)
Keyword(1) Graphene-Oxide-Semiconductor
Keyword(2) Graphene
Keyword(3) Hexagonal Boron Nitride
Keyword(4) Aluminum Oxide
Keyword(5) Low Earth Orbit
1st Author's Name Ren Mutsukawa
1st Author's Affiliation Yokohama National University(YNU)
2nd Author's Name Yoshinori Takao
2nd Author's Affiliation Yokohama National University(YNU)
3rd Author's Name Masayoshi Nagao
3rd Author's Affiliation National Institute of Advanced Industrial Science and Technology(AIST)
4th Author's Name Hiromasa Murata
4th Author's Affiliation National Institute of Advanced Industrial Science and Technology(AIST)
5th Author's Name Katsuhisa Murakami
5th Author's Affiliation National Institute of Advanced Industrial Science and Technology(AIST)
Date 2023-12-08
Paper # ED2023-48
Volume (vol) vol.123
Number (no) ED-297
Page pp.pp.39-42(ED),
#Pages 4
Date of Issue 2023-11-30 (ED)