| Presentation | 2023-11-01 [Invited Talk] Nanographene Synthesis by Polymerization of Pentacene Akira Heya, Koji Sumitomo, |
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| PDF Download Page |  PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Graphene nanoribbons (GNRs) with a width of 1.2 nm are a type of nanographene and are expected to be a next-generation semiconductor material. We have attempted to synthesize GNRs by polymerization of pentacene using Ni supported W-mesh, pentacene, H2 gas, and soft X-ray irradiation. Nanographene (pentacene polymers (N=2-5)) could be synthesized using a W mesh with 3 % Ni coverage (WNi(3%)). The WNi (3%) mesh allows the same amount of pentacene and dihydropentacene to be present on the mesh, which increases the degree of polymerization and the yield of nanographene. Furthermore, graphene was synthesized by soft X-ray irradiation in films containing pentacene polymers fabricated on Ni films, suggesting that hydrogen desorption and catalytic effects on the Ni film surface during soft X-ray irradiation promote Pn polymerization and that pentacene polymers act as nuclei for nanographene formation. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | Nanographene / Pentacene / W mesh supported Ni / Hydrogen gas / Soft X-ray irradiation |
| Paper # | OME2023-43 |
| Date of Issue | 2023-10-25 (OME) |
| Conference Information | |
| Committee | OME |
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| Conference Date | 2023/11/1(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | JIBASAN Bidg. (Himeji) |
| Topics (in Japanese) | (See Japanese page) |
| Topics (in English) | Organic Devices, Sensors, etc. |
| Chair | Eiji Itoh(Shinshu Univ.) |
| Vice Chair | Akira Baba(Niigata Univ.) |
| Secretary | Akira Baba(Univ. of Hyogo) |
| Assistant | Yoshiyuki Seike(Aichi Inst. of Tech.) / PANDEY Shyam sudhir(Kyushu Inst. of Tech.) |
| Paper Information | |
| Registration To | Technical Committee on Organic Molecular Electronics |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | [Invited Talk] Nanographene Synthesis by Polymerization of Pentacene |
| Sub Title (in English) | Effects of Ni supported catalyst and soft X-ray irradiation |
| Keyword(1) | Nanographene |
| Keyword(2) | Pentacene |
| Keyword(3) | W mesh supported Ni |
| Keyword(4) | Hydrogen gas |
| Keyword(5) | Soft X-ray irradiation |
| 1st Author's Name | Akira Heya |
| 1st Author's Affiliation | University of Hyogo(Univ. of Hyogo) |
| 2nd Author's Name | Koji Sumitomo |
| 2nd Author's Affiliation | University of Hyogo(Univ. of Hyogo) |
| Date | 2023-11-01 |
| Paper # | OME2023-43 |
| Volume (vol) | vol.123 |
| Number (no) | OME-237 |
| Page | pp.pp.1-6(OME), |
| #Pages | 6 |
| Date of Issue | 2023-10-25 (OME) |