Presentation 2022-10-28
Microstructure and piezoelectricity of multi-elements doped K0.45Na0.55NbO3 ceramics
Kandai Nagata, Noriko Bamba,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) Potassium sodium niobate (KNN) is one of the most widely studied lead-free piezoelectric materials. In this study, multi-elements doped 0.95(K0.45Na0.55)0.98Li0.02NbO3-0.02BaZrO3-0.03Bi0.5K0.5HfO3 ceramics were fabricated by a two-step sintering method, and the effects of holding times at 1st step and 2nd step (t1 and t2) on the microstructures, The Curie temperature TC and piezoelectric constants d33 were investigated. Densification and grain growth progressed when the holding time t1 at 1150oC was longer than 10 min. The highest density of about 95% was obtained at t1=50 min and t2=15 h. The TC decreased with increasing holding times t1 and t2, presumably due to volatilization of alkali metal elements. The d33 varied from 86 pC/N to 232 pC/N, depending on the compositional change due to the volatilization and the grain size. The grain size dependence of d33 suggested an optimum grain size of 3.0 ~ 3.5 ?m for this KNN solid solution.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Potassium sodium niobate / multi-elements doping / two-step sintering / piezoelectric constant / grain size
Paper # MRIS2022-16,CPM2022-47
Date of Issue 2022-10-20 (MRIS, CPM)

Conference Information
Committee MRIS / CPM / ITE-MMS
Conference Date 2022/10/27(2days)
Place (in Japanese) (See Japanese page)
Place (in English) Shinshu Univ.
Topics (in Japanese) (See Japanese page)
Topics (in English) Spintronics, Solid State Memory, Functional material, Thin film process, Material, Devices, etc.
Chair Ikuya Tagawa(Tohoku Inst. of Tech.) / Yuichi Nakamura(Toyohashi Univ. of Tech.)
Vice Chair / Hideki Nakazawa(Hirosaki Univ.)
Secretary (Ehime Univ.) / Hideki Nakazawa(Samsung) / (Ehime Univ.)
Assistant Nobuaki Kikuchi(Tohoku Univ.) / Toshiki Yamaji(AIST) / Yasuo Kimura(Tokyo Univ. of Tech.) / Fumihiko Hirose(Yamagata Univ.) / Noriko Bamba(Shinshu Univ.)

Paper Information
Registration To Technical Committee on Magnetic Recording & Information Storage / Technical Committee on Component Parts and Materials / Technical Group on Multi-media Storage
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Microstructure and piezoelectricity of multi-elements doped K0.45Na0.55NbO3 ceramics
Sub Title (in English)
Keyword(1) Potassium sodium niobate
Keyword(2) multi-elements doping
Keyword(3) two-step sintering
Keyword(4) piezoelectric constant
Keyword(5) grain size
1st Author's Name Kandai Nagata
1st Author's Affiliation Shinshu University(Shinshu Univ.)
2nd Author's Name Noriko Bamba
2nd Author's Affiliation Shinshu University(Shinshu Univ.)
Date 2022-10-28
Paper # MRIS2022-16,CPM2022-47
Volume (vol) vol.122
Number (no) MRIS-230,CPM-231
Page pp.pp.43-47(MRIS), pp.43-47(CPM),
#Pages 5
Date of Issue 2022-10-20 (MRIS, CPM)