| Presentation | 2019-12-20 Single Crystal Structures and Physical Properties of Porphyrin Derivatives Taku Kato, Sadafumi Nishihara, Tomoyuki Akutagawa, Takayoshi Nakamura, Yoko Tatewaki, |
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| PDF Download Page |  PDF download Page Link |
| Abstract(in Japanese) | (See Japanese page) |
| Abstract(in English) | Porphyrin has been attracting attention for many years in the field of material science because it can be modified in various ways in addition to it’s ability to have which are useful in the studies of optics, electrochemistry, magnetism, and catalytic activity. Porphyrins can be applied to gas adsorbing materials and sensors by utilizing their molecular recognition ability, it can also be said that a cage molecule is useful as a molecular structure. In general, since a cage molecule has a large space in it, it is possible for molecules to be enclosed, to enter and to exit the cage. In other words, it can be considered as a structure that is suitable for gas adsorption and sensors materials. In this study, we synthesized cage-like molecules using porphyrin derivatives as molecular designs. The purpose of this study was to analyze the single crystal X-ray structure and evaluate the physical properties of the molecules using porphyrin derivatives. Single crystals were prepared the synthesized molecules, and single crystal X-ray structural analysis was performed. As a result, planar molecules were confirmed instead of the cage like molecule. From the results of mass spectrometry, it was considered that different molecular crystals were formed since the peaks of the cage and the planar molecule could be observed. |
| Keyword(in Japanese) | (See Japanese page) |
| Keyword(in English) | porphyrin / single crystal x-ray structure analysis |
| Paper # | OME2019-40 |
| Date of Issue | 2019-12-13 (OME) |
| Conference Information | |
| Committee | OME |
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| Conference Date | 2019/12/20(1days) |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | avanc?e (Saga city) |
| Topics (in Japanese) | (See Japanese page) |
| Topics (in English) | organic molecular electronics and photonics, polymer optical materials and devices, etc |
| Chair | Yutaka Majima(Tokyo Inst. of Tech.) |
| Vice Chair | Toshiki Yamada(NICT) |
| Secretary | Toshiki Yamada(Tokyo Inst. of Tech.) |
| Assistant | Toshihiko Kaji(Tokyo Univ. of Agriculture and Tech.) / Yoshiyuki Seike(Aichi Inst. of Tech.) |
| Paper Information | |
| Registration To | Technical Committee on Organic Molecular Electronics |
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| Language | JPN |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Single Crystal Structures and Physical Properties of Porphyrin Derivatives |
| Sub Title (in English) | |
| Keyword(1) | porphyrin |
| Keyword(2) | single crystal x-ray structure analysis |
| 1st Author's Name | Taku Kato |
| 1st Author's Affiliation | Tokyo University of Agliculture and Technology(TUAT) |
| 2nd Author's Name | Sadafumi Nishihara |
| 2nd Author's Affiliation | Hiroshima University(Hiroshima Univ.) |
| 3rd Author's Name | Tomoyuki Akutagawa |
| 3rd Author's Affiliation | Tohoku University(Tohoku Univ.) |
| 4th Author's Name | Takayoshi Nakamura |
| 4th Author's Affiliation | Hokkaido University(Hokkaido Univ.) |
| 5th Author's Name | Yoko Tatewaki |
| 5th Author's Affiliation | Tokyo University of Agliculture and Technology(TUAT) |
| Date | 2019-12-20 |
| Paper # | OME2019-40 |
| Volume (vol) | vol.119 |
| Number (no) | OME-350 |
| Page | pp.pp.21-24(OME), |
| #Pages | 4 |
| Date of Issue | 2019-12-13 (OME) |