Presentation 2019-11-07
Annealing effects on the properties of nitrogen doped DLC films
Hiroya Osanai, Kazuki Nakamura, Haruto Koriyama, Yasuyuki Kobayashi, Yoshiharu Enta, Yushi Suzuki, Maki Suemitsu, Hideki Nakazawa,
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Abstract(in Japanese) (See Japanese page)
Abstract(in English) We have prepared nitrogen doped diamond-like carbon (N-DLC) films by plasma-enhanced chemical vapor deposition using H2 as a dilution gas and investigated the effects of post-annealing in a vacuum on the film properties. We found that optical bandgap slightly increased after post-annealing at 235 to 270°C, suggesting that the density of defect levels in bandgap decreased. On the other hand, it was found that the optical bandgap decreased after post-annealing at 420 to 490°C. At these temperatures, the amount of bound hydrogen in the films tended to decrease, whereas sp2C=C bonds increased and their clustering was enhanced. We examined the current-voltage characteristics of N-DLC/p-type Si heterojunctions and found that the heterojunction annealed at 490°C exhibited the highest rectification ratio.
Keyword(in Japanese) (See Japanese page)
Keyword(in English) Diamond-like carbon / Plasma-enhanced chemical vapor deposition / Nitrogen / Post-annealing
Paper # CPM2019-46
Date of Issue 2019-10-31 (CPM)

Conference Information
Committee CPM
Conference Date 2019/11/7(2days)
Place (in Japanese) (See Japanese page)
Place (in English) Fukui univ.
Topics (in Japanese) (See Japanese page)
Topics (in English)
Chair Mayumi Takeyama(Kitami Inst. of Tech.)
Vice Chair Yuichi Nakamura(Toyohashi Univ. of Tech.)
Secretary Yuichi Nakamura(Hirosaki Univ.)
Assistant Yasuo Kimura(Tokyo Univ. of Tech.) / Tomoaki Terasako(Ehime Univ.) / Fumihiko Hirose(Yamagata Univ.)

Paper Information
Registration To Technical Committee on Component Parts and Materials
Language JPN
Title (in Japanese) (See Japanese page)
Sub Title (in Japanese) (See Japanese page)
Title (in English) Annealing effects on the properties of nitrogen doped DLC films
Sub Title (in English)
Keyword(1) Diamond-like carbon
Keyword(2) Plasma-enhanced chemical vapor deposition
Keyword(3) Nitrogen
Keyword(4) Post-annealing
1st Author's Name Hiroya Osanai
1st Author's Affiliation Hirosaki University(Hirosaki Univ.)
2nd Author's Name Kazuki Nakamura
2nd Author's Affiliation Hirosaki University(Hirosaki Univ.)
3rd Author's Name Haruto Koriyama
3rd Author's Affiliation Hirosaki University(Hirosaki Univ.)
4th Author's Name Yasuyuki Kobayashi
4th Author's Affiliation Hirosaki University(Hirosaki Univ.)
5th Author's Name Yoshiharu Enta
5th Author's Affiliation Hirosaki University(Hirosaki Univ.)
6th Author's Name Yushi Suzuki
6th Author's Affiliation Tohoku University(Tohoku Univ.)
7th Author's Name Maki Suemitsu
7th Author's Affiliation Tohoku University(Tohoku Univ.)
8th Author's Name Hideki Nakazawa
8th Author's Affiliation Hirosaki University(Hirosaki Univ.)
Date 2019-11-07
Paper # CPM2019-46
Volume (vol) vol.119
Number (no) CPM-271
Page pp.pp.9-14(CPM),
#Pages 6
Date of Issue 2019-10-31 (CPM)