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| Presentation | 2018-02-22 14:10 Synthesis and One Dimensional Structures of TTF Derivatives with Crown Ether Tsubasa Takei, Shota Nakamura (TUAT), Sadafumi Nishihara (Hiroshima Univ.), Yoko Tatewaki (TUAT)  OME2017-59 Link to ES Tech. Rep. Archives: OME2017-59 |
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| Abstract | (in Japanese) | (See Japanese page) |
| (in English) | Organic conductors based on Tetrathiafulvalene(TTF) showed the high conductivity at room temperature, after mixing several acceptors. The application of CT complexes have been studied to form the one dimensional nanostructure, for example the nanowires and nanocoils. One the other hand, crown ether have ring structures and form the one dimensional column as ion channel structures. In this study, we report the structures and electric properties of molecular nanowires composed of TTF derivatives. We synthesized TTF derivatives(TTF-ER) having chiral and hydrogen-bonding side chains. The UV spectra of TTF derivatives and their TCNQ, F2TCNQ, F4TCNQ complexes were measured by the diffuse reflection method. CT complexes of TTF-ER and F2TCNQ, F4TCNQ showed the absorption band in 700 - 900 nm, which is assigned to the F4TCNQ anion radicals. The IR spectra of TTF derivatives and CT complexes of TTF-ER and F2TCNQ, F4TCNQ were measured by the ATR method. The CT complexes showed a broad absorption band from 2500 to 3000 cm-1, which mean the charge transfer between electron-donating TTF derivatives and electron-accepting F2TCNQ, F4TCNQ. The nanowires were fabricated on mica substrates by cast techniques. The surface morphology was examined by AFM and SEM. |
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| Keyword | (in Japanese) | (See Japanese page) |
| (in English) | nanowires / CT complexes / nanomaterials / / / / / | |
| Reference Info. | IEICE Tech. Rep., vol. 117, no. 447, OME2017-59, pp. 11-14, Feb. 2018. | |
| Paper # | OME2017-59 | |
| Date of Issue | 2018-02-15 (OME) | |
| ISSN | Print edition: ISSN 0913-5685 Online edition: ISSN 2432-6380 | |
| Copyright and reproduction |
All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034) | |
| Download PDF | OME2017-59 Link to ES Tech. Rep. Archives: OME2017-59 |
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| Conference Information | |
| Committee | OME |
| Conference Date | 2018-02-22 - 2018-02-22 |
| Place (in Japanese) | (See Japanese page) |
| Place (in English) | Tokyo University of Agriculture and Technology |
| Topics (in Japanese) | (See Japanese page) |
| Topics (in English) | organic molecular electronics and photonics, polymer optical materials and devices, etc |
| Paper Information | |
| Registration To | OME |
| Conference Code | 2018-02-OME |
| Language | Japanese |
| Title (in Japanese) | (See Japanese page) |
| Sub Title (in Japanese) | (See Japanese page) |
| Title (in English) | Synthesis and One Dimensional Structures of TTF Derivatives with Crown Ether |
| Sub Title (in English) | |
| Keyword(1) | nanowires |
| Keyword(2) | CT complexes |
| Keyword(3) | nanomaterials |
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| 1st Author's Name | Tsubasa Takei |
| 1st Author's Affiliation | Tokyo University of Agriculture and Technology (TUAT) |
| 2nd Author's Name | Shota Nakamura |
| 2nd Author's Affiliation | Tokyo University of Agriculture and Technology (TUAT) |
| 3rd Author's Name | Sadafumi Nishihara |
| 3rd Author's Affiliation | Hiroshima University (Hiroshima Univ.) |
| 4th Author's Name | Yoko Tatewaki |
| 4th Author's Affiliation | Tokyo University of Agriculture and Technology (TUAT) |
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| Speaker | Author-1 |
| Date Time | 2018-02-22 14:10:00 |
| Presentation Time | 20 minutes |
| Registration for | OME |
| Paper # | OME2017-59 |
| Volume (vol) | vol.117 |
| Number (no) | no.447 |
| Page | pp.11-14 |
| #Pages | 4 |
| Date of Issue | 2018-02-15 (OME) |
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