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Paper Abstract and Keywords
Presentation 2015-10-23 14:15
Crystal Structure Analysis of Non-peripheral Octahexyl Phthalocyanine in Thin Film and Single Crystal
Masashi Ohmori, Chika Nakano, Takuya Higashi, Norimitsu Tohnai, Akihiko Fujii, Masanori Ozaki (Osaka Univ.) OME2015-55 Link to ES Tech. Rep. Archives: OME2015-55
Abstract (in Japanese) (See Japanese page) 
(in English) The molecular packing structure in a thin film of the liquid crystalline phthalocyanine, 1,4,8,11,15,18,22,25 –octahexylphthalocyanine (C6PcH2) and the crystal structure in single crystals of C6PcH2 by X-ray diffraction (XRD) measurement were studied. The crystal structure of C6PcH2 in the thin film was determined to be a centered rectangular structure (a = 36.4 Å、b = 20.3 Å). The tilt angle of the phthalocyanine core normal vector was 34-39º from the column axis, and the stacking period was estimated to be 4.8-5.0 Å. The block and needle-like shape of single crystals were grown by recrystallization. The block and needle-like single crystals were different from not only their shapes but also their crystal structures. The crystal structure of the block single crystal was a reported structure and the needle-like single crystal was a novel structure. It is found that the crystal structure in the thin films must be same as that of the needle-like single crystals by temperature dependency of the lattice constant.
Keyword (in Japanese) (See Japanese page) 
(in English) Crystal Polymorphism / Phthalocyanine / Single Crystal X-ray Structure Analysis / / / / /  
Reference Info. IEICE Tech. Rep., vol. 115, no. 265, OME2015-55, pp. 25-30, Oct. 2015.
Paper # OME2015-55 
Date of Issue 2015-10-16 (OME) 
ISSN Print edition: ISSN 0913-5685    Online edition: ISSN 2432-6380
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All rights are reserved and no part of this publication may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopy, recording, or any information storage and retrieval system, without permission in writing from the publisher. Notwithstanding, instructors are permitted to photocopy isolated articles for noncommercial classroom use without fee. (License No.: 10GA0019/12GB0052/13GB0056/17GB0034/18GB0034)
Download PDF OME2015-55 Link to ES Tech. Rep. Archives: OME2015-55

Conference Information
Committee OME  
Conference Date 2015-10-23 - 2015-10-23 
Place (in Japanese) (See Japanese page) 
Place (in English) Osaka Univ. Nakanoshima Center 
Topics (in Japanese) (See Japanese page) 
Topics (in English) Organic devices and sensors, etc. 
Paper Information
Registration To OME 
Conference Code 2015-10-OME 
Language Japanese 
Title (in Japanese) (See Japanese page) 
Sub Title (in Japanese) (See Japanese page) 
Title (in English) Crystal Structure Analysis of Non-peripheral Octahexyl Phthalocyanine in Thin Film and Single Crystal 
Sub Title (in English)  
Keyword(1) Crystal Polymorphism  
Keyword(2) Phthalocyanine  
Keyword(3) Single Crystal X-ray Structure Analysis  
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1st Author's Name Masashi Ohmori  
1st Author's Affiliation Osaka University (Osaka Univ.)
2nd Author's Name Chika Nakano  
2nd Author's Affiliation Osaka University (Osaka Univ.)
3rd Author's Name Takuya Higashi  
3rd Author's Affiliation Osaka University (Osaka Univ.)
4th Author's Name Norimitsu Tohnai  
4th Author's Affiliation Osaka University (Osaka Univ.)
5th Author's Name Akihiko Fujii  
5th Author's Affiliation Osaka University (Osaka Univ.)
6th Author's Name Masanori Ozaki  
6th Author's Affiliation Osaka University (Osaka Univ.)
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Speaker Author-1 
Date Time 2015-10-23 14:15:00 
Presentation Time 25 minutes 
Registration for OME 
Paper # OME2015-55 
Volume (vol) vol.115 
Number (no) no.265 
Page pp.25-30 
#Pages
Date of Issue 2015-10-16 (OME) 


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